| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Forsyth, Maria
European Commission
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (42/42 displayed)
- 2024Synergistic Combination of Cross-Linked Polymer and Concentrated Ionic Liquid for Electrolytes with High Stability in Solid-State Lithium Metal Batteriescitations
- 2024Effect of the curing agent DETA and its interaction with a rare earth carboxylate as corrosion inhibitor in a hybrid silica-epoxy formulation
- 2024All-Polymer Nanocomposite as Salt-Free Solid Electrolyte for Lithium Metal Batteriescitations
- 2024Biobased Acrylic Latexes/Sodium Carboxymethyl Cellulose Aqueous Binders for Lithium-Ion NMC 811 Cathodescitations
- 2024A Polymer-Binder-Free Approach to Creating Functional LiFePO4 Cathodes by Organic Ionic Plastic Crystal-Derived Ion-Conductive Binders
- 2023Transport Properties and Local Ions Dynamics in LATP‐Based Hybrid Solid Electrolytescitations
- 2023Single‐ion conducting polymer as lithium salt additive in polymerized ionic liquid block copolymer electrolytecitations
- 2022Comparison of the Corrosion Inhibition Ability of Different Coumarate-Based Compounds Incorporated into Waterborne Binderscitations
- 2021Single-Ion Conducting Polymer Nanoparticles as Functional Fillers for Solid Electrolytes in Lithium Metal Batteriescitations
- 2021Application of super-concentrated phosphonium based ionic liquid electrolyte for anode-free lithium metal batteriescitations
- 2021Flame Retardant Polyphosphoester Copolymers as Solid Polymer Electrolyte for Lithium Batteriescitations
- 2021Single-ion polymer/LLZO hybrid electrolytes with high lithium conductivitycitations
- 2021Tuning the Formation and Structure of the Silicon Electrode/Ionic Liquid Electrolyte Interphase in Superconcentrated Ionic Liquidscitations
- 2020Engineering high-energy-density sodium battery anodes for improved cycling with superconcentrated ionic-liquid electrolytescitations
- 2020Toward High‐Energy‐Density Lithium Metal Batteries: Opportunities and Challenges for Solid Organic Electrolytescitations
- 2020Polymerized Ionic Liquid Block Copolymer Electrolytes for All-Solid-State Lithium-Metal Batteriescitations
- 2020Influence of the cyclic vs. linear carbonate segments in the properties and performance of CO2-sourced polymer electrolytes for lithium batteriescitations
- 2019Single-ion conducting poly(ethylene oxide carbonate) as solid polymer electrolyte for lithium batteriescitations
- 2018Ionic liquid electrolytes supporting high energy density in sodium-ion batteries based on sodium vanadium phosphate compositescitations
- 2018The effect of cation chemistry on physicochemical behaviour of superconcentrated NaFSI based ionic liquid electrolytes and the implications for Na battery performancecitations
- 2018New, environmentally friendly, rare earth carboxylate corrosion inhibitors for mild steelcitations
- 2017Probing corrosion initiation at interfacial nanostructures of AA2024-T3citations
- 2017Preparation and characterization of gel polymer electrolytes using poly(ionic liquids) and high lithium salt concentration ionic liquidscitations
- 2016Novel Na+ ion diffusion mechanism in mixed organic-inorganic ionic liquid electrolyte leading to high Na+ transference number and stable, high rate electrochemical cycling of sodium cellscitations
- 2016Reduction of oxygen in a trialkoxy ammonium-based ionic liquid and the role of watercitations
- 2016Stable zinc cycling in novel alkoxy-ammonium based ionic liquid electrolytescitations
- 2016Unexpected effect of tetraglyme plasticizer on lithium ion dynamics in PAMPS based ionomerscitations
- 2016Investigating non-fluorinated anions for sodium battery electrolytes based on ionic liquidscitations
- 2015Ionic transport through a composite structure of N-ethyl-N-methylpyrrolidinium tetrafluoroborate organic ionic plastic crystals reinforced with polymer nanofibrescitations
- 2015The influence of rare earth mercaptoacetate on the initiation of corrosion on AA2024-T3 Part II: The influence of intermetallic compositions within heavily attacked sitescitations
- 2015The influence of rare earth mercaptoacetate on the initiation of corrosion on AA2024-T3 Part I: Average statistics of each intermetallic compositioncitations
- 2015Enhanced ionic mobility in Organic Ionic Plastic Crystal – Dendrimer solid electrolytescitations
- 2015Characterisation of ion transport in sulfonate based ionomer systems containing lithium and quaternary ammonium cationscitations
- 2011Electrochemical reactivity of trihexyl(tetradecyl)phosphonium bis(2,4,4-trimethylpentyl)phosphinate ionic liquid on glassy carbon and AZ31 magnesium alloycitations
- 2011On the use of organic ionic plastic crystals in all solid-state lithium metal batteriescitations
- 2011Aluminium coordination chemistry in ionic liquid/AlCl3 mixtures
- 2011New 'green' corrosion inhibitors based on rare earth compoundscitations
- 2011Transport properties and phase behaviour in binary and ternary ionic liquid electrolyte systems of interest in lithium batteriescitations
- 2010Potentiostatic control of ionic liquid surface film formation on ZE41 magnesium alloycitations
- 2010An azo-spiro mixed ionic liquid electrolyte for lithium metal- LiFePO 4 batteriescitations
- 2010Characterization of the magnesium alloy AZ31 surface in the ionic liquid trihexyl(tetradecyl)phosphonium bis(trifluoromethanesulfonyl)amide
- 2010Proton transport properties in Zwitterion blends with Bronsted acidscitations
Places of action
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article
Potentiostatic control of ionic liquid surface film formation on ZE41 magnesium alloy
Abstract
The generation of potentially corrosion-resistant films on light metal alloys of magnesium have been investigated. Magnesium alloy, ZE41 [Mg−Zn−Rare Earth (RE)-Zr, nominal composition ∼4 wt % Zn, ∼1.7 wt % RE (Ce), ∼0.6 wt % Zr, remaining balance, Mg], was exposed under potentiostatic control to the ionic liquid trihexyl(tetradecyl)phosphonium diphenylphosphate, denoted [P<sub>6,6,6,14</sub>][DPP]. During exposure to this IL, a bias potential, shifted from open circuit, was applied to the ZE41 surface. Electrochemical impedance spectroscopy (EIS) and chronoamperometry (CA) were used to monitor the evolution of film formation on the metal surface during exposure. The EIS data indicate that, of the four bias potentials examined, applying a potential of −200 mV versus OCP during the exposure period resulted in surface films of greatest resistance. Both EIS measurements and scanning electron microscopy (SEM) imaging indicate that these surfaces are substantially different to those formed without potential bias. Time of flight-secondary ion mass spectrometry (ToF-SIMS) elemental mapping of the films was utilized to ascertain the distribution of the ionic liquid cationic and anionic species relative to the microstructural surface features of ZE41 and indicated a more uniform distribution compared with the surface following exposure in the absence of a bias potential. Immersion of the treated ZE41 specimens in a chloride contaminated salt solution clearly indicated that the ionic liquid generated surface films offered significant protection against pitting corrosion, although the intermetallics were still insufficiently protected by the IL and hence favored intergranular corrosion processes.