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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Vitillo, Jenny Grazia
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2018Understanding and Controlling the Dielectric Response of Metal–Organic Frameworkscitations
- 2018Time-resolved operando studies of carbon supported Pd nanoparticles under hydrogenation reactions by X-ray diffraction and absorptioncitations
- 2018On the structure of superbasic (MgO)n sites solvated in a faujasite zeolitecitations
- 2018Structure and Host–Guest Interactions of Perylene–Diimide Dyes in Zeolite L Nanochannelscitations
- 2017Core-Shell Structure of Palladium Hydride Nanoparticles Revealed by Combined X-ray Absorption Spectroscopy and X-ray Diffractioncitations
- 2014Evolution and reversibility of host/guest interactions with temperature changes in a methyl red@palygorskite polyfunctional hybrid nanocompositecitations
- 2012Evolution of host/guest interactions with heating in a palygorskite/methyl red (Maya Red) hybrid composite
- 2012Monolithic nanoporous-crystalline aerogels based on PPOcitations
- 2011Crystal structure refinement of a sepiolite/indigo Maya Blue pigment using molecular modelling and synchrotron diffractioncitations
- 2011Nanoporous crystalline phases of poly(2,6-dimethyl-1,4-phenylene)oxidecitations
- 2011Combined study of structural properties of metal-organic frameworks changing organic linkers and metal centers
- 2011Aerogels and polymorphism of isotactic poly(4-methyl-pentene-1)citations
- 2011Structure and thermodynamic properties of the NaMgH3 perovskitecitations
- 2011Structure-activity relationships of simple molecules adsorbed on MOF materials: in situ experiments vs. theory
- 2010Hydrogen adsorption by δ and ε crystalline phases of syndiotactic polystyrene aerogelscitations
- 2010Storage of hydrogen as a guest of a nanoporous polymeric crystalline phasecitations
- 2010Hydrogen adsorption by delta and epsilon crystalline phases of syndiotactic polystirene aerogelscitations
- 2009CO adsorption on CPO-27-Ni coordination polymer: spectroscopic features and interaction energycitations
- 2009CO adsorption on cpo-27-ni coordination polymercitations
- 2008Oriented TiO2 nanostructured pillar arrayscitations
- 2008Local structure of CPO-27-Ni metallorganic framework upon dehydration and coordination of NOcitations
Places of action
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article
Aerogels and polymorphism of isotactic poly(4-methyl-pentene-1)
Abstract
Monolithic and highly crystalline aerogels of isotactic poly(4-methyl-pentene-1) (i-P4MP1) have been prepared by sudden solvent extraction with supercritical carbon dioxide from thermoreversible gels. The cross-link junctions of i-P4MP1 gels, depending on the solvent, can be constituted by pure polymer crystalline phases (I or III or IV) or by polymer-solvent cocrystalline phases (for cyclohexane and carbon tetrachloride gels). Gels with cocrystalline phases lead to aerogels exhibiting the denser crystalline form II, whereas all the other considered gels lead to aerogels exhibiting the thermodynamically stable form I. Aerogels obtained from form I gels, which do not undergo a crystalline phase transition during the CO(2) extraction process present the high structural stability most suitable for the preparation of porous membranes. The effect of solvents on the aerogel pore structure and morphology has been also investigated by scanning electron microscopy and N(2) sorption measurements. In all cases, the aerogels present highly porous interconnected structures with macropores and mesopores presenting a large size distribution and a vanishing presence of micropores.