| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Reineke, Theresa M.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Mechanical Recycling of 3D-Printed Thermosets for Reuse in Vat Photopolymerizationcitations
- 2023Radical ring-opening polymerization of sustainably-derived thionoisochromanonecitations
- 2023Biobased Copolymers via Cationic Ring-Opening Copolymerization of Levoglucosan Derivatives and ϵ-Caprolactonecitations
- 2023Biobased and degradable thiol-ene networks from levoglucosan for sustainable 3D printingcitations
- 2021Degradable polyanhydride networks derived from itaconic acidcitations
- 2021Structural Basis for the Different Mechanical Behaviors of Two Chemically Analogous, Carbohydrate-Derived Thermosetscitations
- 2021Sustainable advances in SLA/DLP 3D printing materials and processescitations
- 2021Regioregular Polymers from Biobased (R)-1,3-Butylene Carbonatecitations
- 2019Properties of Chemically Cross-Linked Methylcellulose Gelscitations
- 2018Isothermal Titration Calorimetry for the Screening of Aflatoxin B1 Surface-Enhanced Raman Scattering Sensor Affinity Agentscitations
- 2016Acrylic Triblock Copolymers Incorporating Isosorbide for Pressure Sensitive Adhesivescitations
- 2015Isosorbide-based polymethacrylatescitations
- 2014Degradable thermosets from sugar-derived dilactonescitations
- 2012Glucose-functionalized, serum-stable polymeric micelles from the combination of anionic and RAFT polymerizationscitations
Places of action
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article
Acrylic Triblock Copolymers Incorporating Isosorbide for Pressure Sensitive Adhesives
Abstract
<p>A new monomer acetylated acrylic isosorbide (AAI) was prepared in two steps using common reagents without the need for column chromatography. Free radical polymerization of AAI afforded poly(acetylated acrylic isosorbide) (PAAI), which exhibited a glass transition temperature (T<sub>g</sub>) = 95 °C and good thermal stability (T<sub>d</sub>, 5% weight loss; N<sub>2</sub> = 331 °C, air = 291 °C). A series of ABA triblock copolymers with either poly(n-butyl acrylate) (PnBA) or poly(2-ethylhexyl acrylate) (PEHA) as the low T<sub>g</sub> midblocks and PAAI as the high T<sub>g</sub> end blocks were prepared using Reversible Addition-Fragmentation chain Transfer (RAFT) polymerization. The triblock copolymers ranging from 8-24 wt % PAAI were evaluated as pressure sensitive adhesives by 180° peel, loop tack, and static shear testing. While the PAAI-PEHA-PAAI series exhibited poor adhesive qualities, the PAAI-PnBA-PAAI series of triblock copolymers demonstrated peel forces up to 2.9 N cm<sup>-1</sup>, tack forces up to 3.2 N cm<sup>-1</sup>, and no shear failure up to 10 000 min. Dynamic mechanical analysis indicated that PAAI-PEHA-PAAI lacked the dissipative qualities needed to form an adhesive bond with the substrate, while the PAAI-PnBA-PAAI series exhibited a dynamic mechanical response consistent with related high performing PSAs.</p>