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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Wilson, Bp
Aalto University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2023Assessment of environmental sustainability of nickel required for mobility transitioncitations
- 2022Electrochemical Growth of Ag/Zn Alloys from Zinc Process Solutions and Their Dealloying Behaviorcitations
- 2022A New Hydrometallurgical Process for Metal Extraction from Electric Arc Furnace Dust Using Ionic Liquidscitations
- 2022Green and Controllable Preparation of Cu/Zn Alloys Using Combined Electrodeposition and Redox Replacementcitations
- 2022Targeted surface modification of Cu/Zn/Ag coatings and Ag/Cu particles based on sacrificial element selection by electrodeposition and redox replacementcitations
- 2021Cyclic voltammetry and potentiodynamic polarization studies of chalcopyrite concentrate in glycine mediumcitations
- 2021Biopolymeric Anticorrosion Coatings from Cellulose Nanofibrils and Colloidal Lignin Particlescitations
- 2020A sustainable two-layer lignin-anodized composite coating for the corrosion protection of high-strength low-alloy steelcitations
- 2020Investigation of the anticorrosion performance of lignin coatings after crosslinking with triethyl phosphate and their adhesion to a polyurethane topcoat
- 2019Modelling of silver anode dissolution and the effect of gold as impurity under simulated industrial silver electrorefining conditionscitations
- 2018From waste to valuable resource: Lignin as a sustainable anti-corrosion coatingcitations
- 2018A direct synthesis of platinum/nickel co-catalysts on titanium dioxide nanotube surface from hydrometallurgical-type process streamscitations
- 2018Selective reductive leaching of cobalt and lithium from industrially crushed waste Li-ion batteries in sulfuric acid systemcitations
- 2018Kinetic study and modelling of silver dissolution in synthetic industrial silver electrolyte as a function of electrolyte composition and temperaturecitations
- 2017Strongly reduced thermal conductivity in hybrid ZnO/nanocellulose thin filmscitations
- 2017Carbon Nanostructure Based Platform for Enzymatic Glutamate Biosensorscitations
- 2017Leaching of Sb from TROF furnace Doré slagcitations
- 2016Carbon nanotube-copper composites by electrodeposition on carbon nanotube fiberscitations
- 2006Formation of ultra-thin amorphous conversion films on zinc alloy coatingscitations
- 2002Investigating changes in corrosion mechanism induced by laser welding galvanised steel specimens using scanning vibrating electrode techniquecitations
Places of action
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article
Green and Controllable Preparation of Cu/Zn Alloys Using Combined Electrodeposition and Redox Replacement
Abstract
This study outlines a novel and sustainable electrodeposition-redox replacement (EDRR) method to produce Cu/Zn alloys using a simulated hydrometallurgical Zn solution containing 200 ppm Cu, 65 g/L Zn, and 10 g/L H2SO4. The results indicate that by tailoring the EDRR parameters, like deposition time, replacement time, and agitation conditions, Cu/Zn alloys with controllable properties including chemical composition, microstructures, colorations, and crystalline phases can be readily obtained. Scanning electron microscopy (SEM) analysis shows that coherent Cu/Zn films grow from separate nanoscale particles produced during the initial EDRR cycles. Furthermore, the corrosion performance of the prepared Cu/Zn films is tunable by changing the crystalline phases through the variation of operating conditions. For example, deposits containing Zn-rich phases (CuZn5, Cu5Zn8) obtained with short redox replacement times without agitation resulted in relatively poor corrosion resistance. In contrast, Cu-rich phases (Cu0.75Zn0.25, Cu0.85Zn0.15) with enhanced corrosion performance were achieved with prolonged redox replacement times and/or the application of magnetic stirring. Unlike traditional electrodeposition, the EDRR method does not involve any complexing agents and the currently underutilized hydrometallurgical solutions were used as potential raw materials. Overall, the study suggests the EDRR method as a promising approach to achieve sustainable manufacturing of Cu/Zn alloys and an improved circular economy of metals. ; Peer reviewed