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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Tirri, Teija
Åbo Akademi University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2023Dry Reforming of Methane over Ni-Fe-Al Catalysts Prepared by Solution Combustion Synthesiscitations
- 2021On Laccase-Catalyzed Polymerization of Biorefinery Lignin Fractions and Alignment of Lignin Nanoparticles on the Nanocellulose SurfaceviaOne-Pot Water-Phase Synthesiscitations
- 2021On Laccase-Catalyzed Polymerization of Biorefinery Lignin Fractions and Alignment of Lignin Nanoparticles on the Nanocellulose Surface via One-Pot Water-Phase Synthesiscitations
- 2021Sulfenamides as Standalone Flame Retardants for Polystyrenecitations
- 2020Tailored thermosetting wood adhesive based on well-defined hardwood lignin fractionscitations
- 2018The Synthesis of Low-Viscosity Organotin-Free Moisture-Curable Silane-Terminated Poly(Urethane-Urea)scitations
- 2017Investigation on the Influence of Chain Extenders on the Performance of One-Component Moisture-Curable Polyurethane Adhesivescitations
- 2016Structure–Property Studies on a New Family of Halogen Free Flame Retardants Based on Sulfenamide and Related Structurescitations
- 2015The effect of core-shell particle morphology on adhesive properties of poly(styrene-co-butyl acrylate)citations
- 2013Flame retardant polyurethane nanocomposite: Study of clay dispersion and its synergistic effect with dolomitecitations
Places of action
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article
Tailored thermosetting wood adhesive based on well-defined hardwood lignin fractions
Abstract
By aiming at tailoring the bonding strength of a thermosetting lignin-containing phenol-formaldehyde (LPF) wood adhesive, different fractions of an industrial hardwood alkaline lignin have been prepared through sequential solvent fractionation ( i -PrOH, EtOH, and MeOH). Those fractions were comprehensively characterized by GPC, GC, Py/GC–MS, and NMR techniques. Lignin fractions with low molar mass and narrow dispersity, including the i -PrOH-soluble and EtOH-soluble ones, were of high purity and had more reactive sites for LPF adhesive synthesis and better accessibility due to lower degree of condensation than the high molar mass ones. Some recalcitrance of integrating high molar mass fractions covalently into the PF adhesive was observed, which was also true in the case of lignin phenolation. The tailored bonding strength of the LPF adhesive, tested by gluing wood pieces, provided strong evidence for molecular structure–performance correlation; the i -PrOH-PF had the lowest activation energy, the highest curing enthalpy, and the strongest bonding strength of 2.16 MPa. This study demonstrates a clear structure–property-application relationship of technical hardwood lignin in the LPF adhesive field, which might pave the way for a more effective bulk valorization.