| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Vicent-Luna, José Manuel
Eindhoven University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Adsorption Characteristics of Refrigerants for Thermochemical Energy Storage in Metal–Organic Frameworkscitations
- 2024Adapted thermodynamical model for the prediction of adsorption in nanoporous materialscitations
- 2022Transferable Classical Force Field for Pure and Mixed Metal Halide Perovskites Parameterized from First-Principlescitations
- 2021Efficient Computation of Structural and Electronic Properties of Halide Perovskites Using Density Functional Tight Bindingcitations
- 2021Atomistic Insights Into the Degradation of Inorganic Halide Perovskite CsPbI3citations
- 2021Atomistic Insights Into the Degradation of Inorganic Halide Perovskite CsPbI3:A Reactive Force Field Molecular Dynamics Studycitations
- 2021Efficient Computation of Structural and Electronic Properties of Halide Perovskites Using Density Functional Tight Binding:GFN1-xTB Methodcitations
- 2020Further Extending the Dilution Range of the “Solvent-in-DES” Regime upon the Replacement of Water by an Organic Solvent with Hydrogen Bond Capabilitiescitations
- 2020Efficient modelling of ion structure and dynamics in inorganic metal halide perovskitescitations
- 2018Role of Ionic Liquid [EMIM]+[SCN]- in the Adsorption and Diffusion of Gases in Metal-Organic Frameworkscitations
- 2016Liquid self-diffusion of H2O and DMF molecules in Co-MOF-74citations
- 2016Storage and Separation of Carbon Dioxide and Methane in Hydrated Covalent Organic Frameworkscitations
Places of action
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article
Further Extending the Dilution Range of the “Solvent-in-DES” Regime upon the Replacement of Water by an Organic Solvent with Hydrogen Bond Capabilities
Abstract
<p>Aqueous dilutions of deep eutectic solvents (DESs) have lately allowed exploring new and more demanding applications where neat DESs are not able to perform well. However, the use of DES dilutions with nonaqueous hydrogen-bond-forming solvents remains basically unexplored. It is worth noting the obvious interest of using organic solvents in those cases where any reagent or byproduct is nonsoluble, nonmiscible, or unstable in water, the presence of water might alter the reaction kinetics (for instance, when water is a byproduct), or a cosolvent with low vapor pressure allows exploring reaction processes (high temperatures or solvothermal conditions, among others) not suitable for water. Herein, we investigated benzyl alcohol (BA) dilutions of RUChCl, a DES composed of resorcinol (R), urea (U), and choline chloride (ChCl). In particular, neutron scattering, nuclear magnetic resonance, and Brillouin experiments revealed how BA was accommodated within the hydrogen-bond (HB) complex structure of RUChCl for BA contents of up to 67 wt % whereas this HB complex structure basically disappeared for higher BA contents. This behavior somehow resembled that found in aqueous solutions, with two well-differentiated regimes-e.g., the "solvent-in-DES"and the "DES-in-solvent"-depending on the DES content. However, the "solvent-in-DES"regime was preserved for much higher solvent contents of BA than H2O-e.g., 60-65 versus 18-20 wt %, respectively. Interestingly, the specific BA dilution where transition from one regime to the other occurs was particularly well suited to develop a spinodal decomposition process when used as the precursor for the preparation of polymer resins (by polycondensation between R and p-phthalaldehyde).</p>