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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Cataldi, Pietro
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Topics
Publications (13/13 displayed)
- 2022Hazard Assessment of Abraded Thermoplastic Composites Reinforced with Reduced Graphene Oxidecitations
- 20223D cellulose fiber networks modified by PEDOT:PSS/graphene nanoplatelets for thermoelectric applicationscitations
- 2021Zinc Polyaleuritate Ionomer Coatings as a Sustainable, Alternative Technology for Bisphenol A-Free Metal Packagingcitations
- 2020Plant-Inspired Polyaleuritate–Nanocellulose Composite Photonic Filmscitations
- 2020Green Biocomposites for Thermoelectric Wearable Applicationscitations
- 2020Sustainable, high barrier polyaleuritate/nanocellulose biocompositescitations
- 2020Multifunctional Biocomposites Based on Polyhydroxyalkanoate and Graphene/Carbon Nanofiber Hybrids for Electrical and Thermal Applicationscitations
- 2019Green Biocomposites for Thermoelectric Wearable Applicationscitations
- 2019Keratin-Graphene Nanocomposite: Transformation of Waste Wool in Electronic Devicescitations
- 2018Fully-sprayed flexible polymer solar cells with a cellulose-graphene electrodecitations
- 2018Graphene Nanoplatelets-Based Advanced Materials and Recent Progress in Sustainable Applicationscitations
- 2016Effect of graphene nano-platelet morphology on the elastic modulus of soft and hard biopolymerscitations
- 2016Effect of graphene nano-platelet morphology on the elastic modulus of soft and hard biopolymerscitations
Places of action
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article
Sustainable, high barrier polyaleuritate/nanocellulose biocomposites
Abstract
Free-standing and flexible biocomposite films formed by a polyaleuritate matrix and nanocellulose fillers (i.e., cellulose nanofibrils) have been fabricated by a sustainable process. For this, 9,10,16-trihydroxyhexadecanoic (aleuritic) acid from shellac and nanocellulose were blended at different ratios in water through a sonication process. Polymerization of the polyhydroxylated fatty acid into polyaleuritate was induced by a solvent-free, melting poly-condensation reaction in oven. These biocomposites were characterized to evaluate their chemical (by ATR-FTIR spectroscopy) and physical (e.g., density, thermal stability, rigidity, gas permeability, surface energy, etc.) properties. The compatibility between the polyester matrix and the polysaccharide fillers was excellent due to the interaction by H-bonds of the polar groups of both components. The addition of nanocellulose increased all determined mechanical parameters as well as the wettability and the barrier properties, while the thermal stability and the water uptake were determined by the polyaleuritate matrix. The physical properties of these biocomposites were compared to those of petroleum-based plastics and bio-based polymers indicates that the developed materials can represent a sustainable alternative for different applications such as packaging.