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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ravnsbæk, Dorthe Bomholdt
Aarhus University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2023All-solid-state sodium-ion batteries operating at room temperature based on NASICON-type NaTi2(PO4)3 cathode and ceramic NASICON solid electrolytecitations
- 2022An Easy‐to‐Use Custom‐Built Cell for Neutron Powder Diffraction Studies of Rechargeable Batteriescitations
- 2021Synthesis and Thermal Degradation of MAl4(OH)12SO4·3H2O with M = Co2+, Ni2+, Cu2+, and Zn2+citations
- 2021Understanding disorder in oxide-based electrode materials for rechargeable batteriescitations
- 2021Synthesis and Thermal Degradation of MAl 4 (OH) 12 SO 4 ·3H 2 O with M = Co 2+ , Ni 2+ , Cu 2+ , and Zn 2+citations
- 2020The Effect of oxygen defects on the structural evolution of LiVPO4F1−yoy cathode materialscitations
- 2020On the synthesis and structure of the copper-molybdenum oxide bronzes
- 2017Synthesis, structure and properties of bimetallic sodium rare-earth (RE) borohydrides, NaRE(BH4)4, RE = Ce, Pr, Er or Gdcitations
- 2017Nanoconfined NaAlH4 Conversion Electrodes for Li Batteriescitations
- 2016Synthesis, structure and properties of new bimetallic sodium and potassium lanthanum borohydridescitations
- 2015Manganese borohydride; synthesis and characterizationcitations
- 2014A novel intermediate in the LiAlH4–LiNH2 hydrogen storage systemcitations
- 2014Hydrogen reversibility of LiBH₄-MgH₂-Al compositescitations
- 2011Novel metal boroydrides: Studies of synthesis, crystal chemistry and thermal decomposition
Places of action
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article
Nanoconfined NaAlH4 Conversion Electrodes for Li Batteries
Abstract
<p>In the past, sodium alanate, NaAlH<sub>4</sub>, has been widely investigated for its capability to store hydrogen, and its potential for improving storage properties through nanoconfinement in carbon scaffolds has been extensively studied. NaAlH<sub>4</sub> has recently been considered for Li-ion storage as a conversion-Type anode in Li-ion batteries. Here, NaAlH<sub>4</sub> nanoconfined in carbon scaffolds as an anode material for Li-ion batteries is reported for the first time. Nanoconfined NaAlH<sub>4</sub> was prepared by melt infiltration into mesoporous carbon scaffolds. In the first cycle, the electrochemical reversibility of nanoconfined NaAlH<sub>4</sub> was improved from around 30 to 70% compared to that of nonconfined NaAlH<sub>4</sub>. Cyclic voltammetry revealed that nanoconfinement alters the conversion pathway, and operando powder X-ray diffraction showed that the conversion from NaAlH<sub>4</sub> into Na<sub>3</sub>AlH<sub>6</sub> is favored over the formation of LiNa<sub>2</sub>AlH<sub>6</sub>. The electrochemical reactivity of the carbon scaffolds has also been investigated to study their contribution to the overall capacity of the electrodes.</p>