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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Casavola, Marianna
University of Southampton
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (4/4 displayed)
- 2024Fluidized bed chemical vapor deposition on hard carbon powders to produce composite energy materials
- 2019Anisotropic Plasmonic CuS Nanocrystals as a Natural Electronic Material with Hyperbolic Optical Dispersioncitations
- 2019Anisotropic Plasmonic CuS Nanocrystals as a Natural Electronic Material with Hyperbolic Optical Dispersioncitations
- 2009Exchange-Coupled Bimagnetic Cobalt/Iron Oxide Branched Nanocrystal Heterostructurescitations
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article
Fluidized bed chemical vapor deposition on hard carbon powders to produce composite energy materials
Abstract
Herein, we report a general route for the uniform coating of hard carbon (HC) powders via fluidized bed chemical vapor deposition. Carbon-based fine powders are excellent substrate materials for many catalytic and electrochemical applications but intrinsically difficult to fluidize and prone to elutriation. The reactor was designed to achieve as much retention of powders as possible, supported by a computational fluid dynamics study to assess the hydrodynamic behavior for varying gaseous flow rates. Solutions of the tin seleno- and thio-ether complexes [SnCl<sub>4</sub>{<sup>n</sup>BuSe(CH<sub>2</sub>)<sub>3</sub>Se<sup>n</sup>Bu}] and [SnCl<sub>4</sub>{<sup>n</sup>BuS(CH<sub>2</sub>)<sub>3</sub>S<sup>n</sup>Bu}] were used as single source precursors and injected at high temperature into a fluidized bed of HC powders under nitrogen flow. The method allowed for the synthesis of HC-SnS<sub>x</sub>–SnSe<sub>2</sub> composites at the gram scale with potential applications in electrocatalysis and sodium-ion battery anodes.