| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Pons, Josefina
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2020Influence of Aromatic Cations on the Structural Arrangement of Hg(II) Halidescitations
- 2019Polymorphism and Supramolecular Isomerism : The Impasse of Coordination Polymers
- 2015New binuclear copper(II) coordination polymer based on mixed pyrazolic and oxalate ligands: structural characterization and mechanical propertiescitations
- 2013Study of new metallomacrocyclic Pd(ii) complexes based on hybrid pyrazole sulfoxide/sulfone ligands and their contribution to supramolecular networkscitations
- 2011Variable behaviour of flexible N,O-mixed pyrazole ligand towards Zn(ii), Cd(ii) and Hg(ii) ions. Synthesis, crystal structure and fluorescent propertiescitations
- 2010Synthesis, X-ray crystal structure and NMR characterisation of mononuclear Pd(II) and Pt(II) complexes of didentate ligands with NN′-donor setcitations
- 2010Synthesis and characterization of new N-alkylamino-3,5-diphenylpyrazole ligands and reactivity toward PdII and PtII. Study of the cis-trans isomerizationcitations
- 2009Reactivity of [PdCl(bdtp)](BF4) with monodentate neutral and anionic ligands. Structure of [Pd(bdtp)(PPh3)](BF4)2 (bdtp = 1,5-bis(3,5-dimethyl-1-pyrazolyl)-3-thiapentane)citations
- 2008Synthesis, characterization and X-ray crystal structure determination of cyclopalladated [Csp2,N,N′]-, zwitterionic and chelated compounds in the reaction of 3,5-diphenyl-N-alkylaminopyrazole derived ligands with Pd(II)citations
- 2007Preparation and structural characterisation of a Cd(II) complex with unusual geometrycitations
- 2006Synthesis of new palladium(II) compounds with several bidentate nitrogen-donor ligands: Structural analyses by 1H and 13C{1H} NMR spectroscopy and crystal structurescitations
- 2003Synthesis, X-ray crystal structure, and NMR characterisation of thiolate-bridged dinuclear Ni(II), Pd(II) and Pt(II) complexes of didentate ligands with NS-donor setcitations
- 2003Synthesis, characterisation, and X-ray crystal structure of new Ni II, PdII, and PtII complexes of tridentate pyrazole-based ligands with an NOS-donor setcitations
Places of action
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article
Influence of Aromatic Cations on the Structural Arrangement of Hg(II) Halides
Abstract
<p>Understanding the structure and arrangement of hybrid metal halides and their contribution to the optoelectronic properties is, thus far, a challenging topic. In particular, new materials composed of d10 metal halides and pyridinium cations are still largely unexplored. Therefore, we report the synthesis and characterization of six Hg(II) salts built up from (Hg2Cl6)2- or (HgX4)2- anions (X = Cl, Br, I) and 2,2′-bipyridium (2,2′-Hbipy)+, 2,2′-bipyridine-1,1′-diium (2,2′-H2bipy)2+, or 1,10-phenantrolinium (1,10-Hphen)+ cations, using the same experimental conditions. All of them have been characterized by PXRD, EA, FTIR-ATR, and 1H NMR spectroscopies; single-crystal X-ray diffraction; and TG/DTA determinations. The study of their packing via Hirshfeld surface analysis and 3D deformation density mapping revealed the contributions of the intermolecular interactions to the structural arrangement, notably, the effect of the cation planarity on them. Successively, periodic DFT calculations showed that (i) the valence and conducting bands are mainly composed of the p orbitals of the halide and the organic cation, respectively, and (ii) the corresponding band gap depends mainly on the halide. </p>