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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Vernoux, Philippe
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Pd loading threshold for an efficient noble metal use in Pd/CeO2 methane oxidation catalystscitations
- 2021Successive Strong Electrostatic Adsorptions of [RhCl6]3– on Tungstated-Ceria as an Original Approach to Preserve Rh Clusters From Sintering Under High-Temperature Reductioncitations
- 2020Catalytic and Electrochemical Properties of Ag Infiltrated Perovskite Coatings for Propene Deep Oxidationcitations
- 2019Catalytic Properties of Double Substituted Lanthanum Cobaltite Nanostructured Coatings Prepared by Reactive Magnetron Sputteringcitations
- 2019In situ observation of nanoparticle exsolution from Perovskite oxides:from atomic scale mechanistic insight to nanostructure tailoringcitations
- 2019In situ observation of nanoparticle exsolution from perovskite oxidescitations
- 2018Tuning the $mathrm{Pt/CeO_{2}}$ Interface by in Situ Variation of the Pt Particle Sizecitations
- 2016NO 2 -selective electrochemical sensors for Diesel exhaustscitations
- 2016Development of a NOx gas sensor for exhaust
- 2011Improvement of the NOx selectivity for a planar YSZ sensorcitations
- 2009Physicochemical Origins of Electrochemical Promotion of LSM/YSZcitations
- 2005Electrochemical and catalytic properties of porous Pt–YSZ compositescitations
Places of action
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article
In situ observation of nanoparticle exsolution from perovskite oxides
Abstract
<p>Understanding and controlling the formation of nanoparticles at the surface of functional oxide supports is critical for tuning activity and stability for catalytic and energy conversion applications. Here, we use a latest generation environmental transmission electron microscope to follow the exsolution of individual nanoparticles at the surface of perovskite oxides, with ultrahigh spatial and temporal resolution. Qualitative and quantitative analysis of the data reveals the atomic scale processes that underpin the formation of the socketed, strain-inducing interface that confers exsolved particles their exceptional stability and reactivity. This insight also enabled us to discover that the shape of exsolved particles can be controlled by changing the atmosphere in which exsolution is carried out, and additionally, this could also produce intriguing heterostructures consisting of metal-metal oxide coupled nanoparticles. Our results not only provide insight into the in situ formation of nanoparticles but also demonstrate the tailoring of nanostructures and nanointerfaces.</p>