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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Luxa, Jan
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Patterning of COC Polymers by Middle‐Energy Ion Beams for Selective Cell Adhesion in Microfluidic Devicescitations
- 2024Reaction mechanism and performance of innovative 2D germanane‐silicane alloys: SixGe1−xH electrodes in lithium‐ion batteriescitations
- 2024Electrochemical Intercalation and Exfoliation of CrSBr into Ferromagnetic Fibers and Nanoribbonscitations
- 2023Electrochemical Decalcification-Exfoliation of Two-Dimensional Siligene, SixGey: Material Characterization and Perspectives for Lithium-Ion Storagecitations
- 2022Two-dimensional layered chromium selenophosphate: advanced high-performance anode material for lithium-ion batteriescitations
- 2022Unraveling the Mechanism of the Persistent Photoconductivity in InSe and its Doped Counterpartscitations
- 2022Improved Electrochemical Performance of NTs-WS2@C Nanocomposites for Lithium-Ion and Sodium-Ion Batteriescitations
- 2021Functionalized germanane/SWCNT hybrid films as flexible anodes for lithium-ion batteriescitations
- 2020Microwave-Induced Structural Engineering and Pt Trapping in 6R-TaS2 for the Hydrogen Evolution Reactioncitations
- 2020Chemistry of Germanene: Surface Modification of Germanane Using Alkyl Halidescitations
- 20172H → 1T phase engineering of layered tantalum disulphides in electrocatalysis: oxygen reduction reactioncitations
- 2017Surface properties of MoS2 probed by inverse gas chromatography and their impact on electrocatalytic propertiescitations
Places of action
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article
Electrochemical Decalcification-Exfoliation of Two-Dimensional Siligene, SixGey: Material Characterization and Perspectives for Lithium-Ion Storage
Abstract
A two-dimensional (2D) silicene-germanene alloy,siligene(Si x Ge y ),a single-phase material, has attracted increased attention due toits two-elemental low-buckled composition and unique physics and chemistry.This 2D material has the potential to address the challenges causedby low electrical conductivity and the environmental instability ofcorresponding monolayers. Yet, the siligene structure was studiedin theory, demonstrating the material's great electrochemicalpotential for energy storage applications. The synthesis of free-standingsiligene remains challenging and therefore hinders the research andits application. Herein we demonstrate nonaqueous electrochemicalexfoliation of a few-layer siligene from a Ca1.0Si1.0Ge1.0 Zintl phase precursor. The procedure wasconducted in an oxygen-free environment applying a -3.8 V potential.The obtained siligene exhibits a high quality, high uniformity, andexcellent crystallinity; the individual flake is within the micrometerlateral size. The 2D Si x Ge y was further explored as an anode material for lithium-ionstorage. Two types of anode have been fabricated and integrated intolithium-ion battery cells, namely, (1) siligene-graphene oxidesponges and (2) siligene-multiwalled carbon nanotubes. Theas-fabricated batteries both with/without siligene exhibit similarbehavior; however there is an increase in the electrochemical characteristicsof SiGe-integrated batteries by 10%. The corresponding batteries exhibita 1145.0 mAh center dot g(-1) specific capacity at 0.1 A center dot g(-1). The SiGe-integrated batteries demonstrate a verylow polarization, confirmed by their good stability after 50 workingcycles and a decrease in the solid electrolyte interphase level thatoccurs after the first discharge/charge cycle. We anticipate the growingpotential of emerging two-component 2D materials and their great promisefor energy storage and beyond.