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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Vasileiadis, Thomas
Adam Mickiewicz University in Poznań
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2023Understanding the Photothermal and Photocatalytic Mechanism of Polydopamine Coated Gold Nanorodscitations
- 2023Understanding the Photothermal and Photocatalytic Mechanism of Polydopamine Coated Gold Nanorodscitations
- 2022Optomechanical Hot-Spots in Metallic Nanorod–Polymer Nanocompositescitations
- 2022Optomechanical Hot-Spots in Metallic Nanorod–Polymer Nanocompositescitations
- 2020Frequency-domain study of nonthermal gigahertz phonons reveals Fano coupling to charge carrierscitations
- 2019Ultrafast Energy Flow and Structural Changes in Nanoscale Heterostructures
- 2018Ultrafast Heat Flow in Heterostructures of Au Nanoclusters on Thin Films Atomic Disorder Induced by Hot Electronscitations
Places of action
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article
Optomechanical Hot-Spots in Metallic Nanorod–Polymer Nanocomposites
Abstract
Plasmonic coupling between adjacent metallic nanoparticles can be exploited for acousto-plasmonics, single-molecule sensing, and photochemistry. Light absorption or electron probes can be used to study plasmons and their interactions, but their use is challenging for disordered systems and colloids dispersed in insulating matrices. Here, we investigate the effect of plasmonic coupling on optomechanics with Brillouin light spectroscopy (BLS) in a prototypical metal–polymer nanocomposite, gold nanorods (Au NRs) in polyvinyl alcohol. The intensity of the light inelastically scattered on thermal phonons captured by BLS is strongly affected by the wavelength of the probing light. When light is resonant with the transverse plasmons, BLS reveals mostly the normal vibrational modes of single NRs. For lower energy off-resonant light, BLS is dominated by coupled bending modes of NR dimers. The experimental results, supported by optomechanical calculations, document plasmonically enhanced BLS and reveal energy-dependent confinement of coupled plasmons close to the tips of NR dimers, generating BLS hot-spots. Our work establishes BLS as an optomechanical probe of plasmons and promotes nanorod–soft matter nanocomposites for acousto-plasmonic applications.