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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Sturala, Jiri
University of Chemistry and Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (5/5 displayed)
- 2022Universal Capacitance Boost—Smart Surface Nanoengineering by Zwitterionic Molecules for 2D MXene Supercapacitorcitations
- 2022Improved Electrochemical Performance of NTs-WS2@C Nanocomposites for Lithium-Ion and Sodium-Ion Batteriescitations
- 2021Functionalized germanane/SWCNT hybrid films as flexible anodes for lithium-ion batteriescitations
- 2021Functionalized Germanene-Based Nanomaterials for the Detection of Single Nucleotide Polymorphismcitations
- 2020Chemistry of Germanene: Surface Modification of Germanane Using Alkyl Halidescitations
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article
Chemistry of Germanene: Surface Modification of Germanane Using Alkyl Halides
Abstract
Two-dimensional materials attract enormous attention across several scientific fields. The current demands in nano- and optoelectronics, semiconductors, or in catalysis have been accelerating the research process in the field of 2D materials. Among the 14th group 2D materials besides graphene and silicene, layered germanium represents a promising candidate for another class of materials, and its functionalization represents a way to tune either its electronic or optical properties. Here, the exfoliation and functionalization of germanane surface is achieved via abstraction of hydrogen from Ge-H bond and its subsequent alkylation utilizing n-alkyl halides or trifluoromethyl (CF3) group containing benzyl halides. Composition of materials is confirmed by several methods including FT-IR, Raman, X-ray photoelectron, and energy-dispersive X-ray spectroscopy as well as X-ray powder diffraction. Scanning and transmission electron spectroscopy is used to reveal the layered morphology of functionalized germananes. Copyright © 2020 American Chemical Society.