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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Luxa, Jan
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Patterning of COC Polymers by Middle‐Energy Ion Beams for Selective Cell Adhesion in Microfluidic Devicescitations
- 2024Reaction mechanism and performance of innovative 2D germanane‐silicane alloys: SixGe1−xH electrodes in lithium‐ion batteriescitations
- 2024Electrochemical Intercalation and Exfoliation of CrSBr into Ferromagnetic Fibers and Nanoribbonscitations
- 2023Electrochemical Decalcification-Exfoliation of Two-Dimensional Siligene, SixGey: Material Characterization and Perspectives for Lithium-Ion Storagecitations
- 2022Two-dimensional layered chromium selenophosphate: advanced high-performance anode material for lithium-ion batteriescitations
- 2022Unraveling the Mechanism of the Persistent Photoconductivity in InSe and its Doped Counterpartscitations
- 2022Improved Electrochemical Performance of NTs-WS2@C Nanocomposites for Lithium-Ion and Sodium-Ion Batteriescitations
- 2021Functionalized germanane/SWCNT hybrid films as flexible anodes for lithium-ion batteriescitations
- 2020Microwave-Induced Structural Engineering and Pt Trapping in 6R-TaS2 for the Hydrogen Evolution Reactioncitations
- 2020Chemistry of Germanene: Surface Modification of Germanane Using Alkyl Halidescitations
- 20172H → 1T phase engineering of layered tantalum disulphides in electrocatalysis: oxygen reduction reactioncitations
- 2017Surface properties of MoS2 probed by inverse gas chromatography and their impact on electrocatalytic propertiescitations
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article
Chemistry of Germanene: Surface Modification of Germanane Using Alkyl Halides
Abstract
Two-dimensional materials attract enormous attention across several scientific fields. The current demands in nano- and optoelectronics, semiconductors, or in catalysis have been accelerating the research process in the field of 2D materials. Among the 14th group 2D materials besides graphene and silicene, layered germanium represents a promising candidate for another class of materials, and its functionalization represents a way to tune either its electronic or optical properties. Here, the exfoliation and functionalization of germanane surface is achieved via abstraction of hydrogen from Ge-H bond and its subsequent alkylation utilizing n-alkyl halides or trifluoromethyl (CF3) group containing benzyl halides. Composition of materials is confirmed by several methods including FT-IR, Raman, X-ray photoelectron, and energy-dispersive X-ray spectroscopy as well as X-ray powder diffraction. Scanning and transmission electron spectroscopy is used to reveal the layered morphology of functionalized germananes. Copyright © 2020 American Chemical Society.