| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Yamauchi, Yusuke
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2024Dealloying Strategies for Mesoporous AuCu Nanoparticles: Impact on Internal Metallic Structure and Electrocatalytic Performancecitations
- 2024Selection of Fe as a barrier for manufacturing low-cost MgB2 multifilament wires - Advanced microscopy study between Fe and B reactioncitations
- 2023Weak Bonds, Strong Effectscitations
- 2023Flexible Nanoarchitectonics for Biosensing and Physiological Monitoring Applicationscitations
- 2023Mesoporous multimetallic nanospheres with exposed highly entropic alloy sitescitations
- 2023High entropy alloying strategy for accomplishing quintuple-nanoparticles grafted carbon towards exceptional high-performance overall seawater splittingcitations
- 2022Multifunctional materials for photo-electrochemical water splittingcitations
- 2022Plasma-Induced Nanocrystalline Domain Engineering and Surface Passivation in Mesoporous Chalcogenide Semiconductor Thin Filmscitations
- 2022Efficient lithium-ion storage using a heterostructured porous carbon framework and its in situ transmission electron microscopy studycitations
- 2021Self-templated fabrication of hierarchical hollow manganese-cobalt phosphide yolk-shell spheres for enhanced oxygen evolution reactioncitations
- 2020Photodegradation Activity of Poly(ethylene oxide-b-<i>ε</i>-caprolactone)-Templated Mesoporous TiO<sub>2</sub> Coated with Au and Ptcitations
- 2020Holey assembly of two-dimensional iron-doped nickel-cobalt layered double hydroxide nanosheets for energy conversion applicationcitations
- 2020Potassium-Ion Storage in Cellulose-Derived Hard Carboncitations
- 2019Reduced Graphene Oxide (rGO) Prepared by Metal-Induced Reduction of Graphite Oxidecitations
- 2019Enhancement of thermoelectric properties of La-doped SrTiO <sub>3</sub> bulk by introducing nanoscale porositycitations
- 2018Graphene-oxide-loaded superparamagnetic iron oxide nanoparticles for ultrasensitive electrocatalytic detection of microRNAcitations
- 2017Self-assembly of polymeric micelles made of asymmetric polystyrene-b-polyacrylic acid-b-polyethylene oxide for the synthesis of mesoporous nickel ferritecitations
- 2017Nano-micro-porous skutterudites with 100% enhancement in ZT for high performance thermoelectricitycitations
- 2016Cyano-Bridged Trimetallic Coordination Polymer Nanoparticles and Their Thermal Decomposition into Nanoporous Spinel Ferromagnetic Oxidescitations
Places of action
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article
Weak Bonds, Strong Effects
Abstract
<p>Halogen bonding (HaB) is a weak interaction that assists in the recognition of nucleophilic molecules. However, HaB elements are currently under-investigated as a part of functional materials in separation science. Herein, we develop a novel approach for introducing HaB elements into UiO-66 to fine-tune the adsorption properties toward chlorobenzenes (CBs). A series of UiO-66 containing various contents of 2-iodoterephtalic acid (I-TA) (0%, 33%, 50%, 67%, and 100%) was prepared, characterized, and applied for the selective removal of CB contaminants from nonchlorinated aromatic analogues that cannot be separated by common distillation. Investigation of the structure-property relationship revealed that the highest adsorption capacity was achieved in the case of UiO-66 loaded with 50% I-TA (UiO-66-I<sub>opt</sub>), and this was attributed to the balance between the number of HaB elements and the surface area of the UiO-66 structure. According to density functional theory calculations, the formation of a conjugate between dichlorobenzene and UiO-66-I<sub>opt</sub> was more energetically favorable (up to 1.7 kcal/mol) than that of the corresponding conjugate with UiO-66. The formation of HaBs was experimentally verified by UV-vis, Raman, and X-ray photoelectron spectroscopies. To obtain functional materials for separation applications, waste polyethylene terephthalate (PET) was used as a support and feedstock for the surface-assisted growth of UiO-66-I<sub>opt</sub>. The as-prepared PET@UiO-66-I<sub>opt</sub> exhibited a close-to-perfect selectivity and reusability for the separation of a wide range of CBs from nonchlorinated aromatic analogues.</p>