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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Pich, Andrij
Maastricht University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2024Enhancing Adhesion of Fibrin-Based Hydrogel to Polythioether Polymer Surfacescitations
- 2023Novel Pectin Binder for Satelliting Carbides to H13 Tool Steel for PBF-LB Processingcitations
- 2022Characterization of transient rheological behavior of soft materials using ferrofluid dropletscitations
- 2022Generation of local diffusioosmotic flow by light responsive microgelscitations
- 2021Post-Modification of Biobased Pyrazines and Their Polyesterscitations
- 2020Stimuli-Responsive Zwitterionic Core-Shell Microgels for Antifouling Surface Coatingscitations
- 2020Amphiphilic PVCL/TBCHA microgelscitations
- 2020Ranking of fiber composites by estimation of types and mechanisms of their fracturecitations
- 2020Polyphosphazene-Tannic Acid Colloids as Building Blocks for Bio-Based Flame-Retardant Coatingscitations
- 2020Mononuclear zinc(II) Schiff base complexes as catalysts for the ring-opening polymerization of lactidecitations
- 2020Dual-Temperature-Responsive Microgels from a Zwitterionic Functional Graft Copolymer with Superior Protein Repelling Propertycitations
- 2019Heterolepic β ‐Ketoiminate Zinc Phenoxide Complexes as Efficient Catalysts for the Ring Opening Polymerization of Lactidecitations
- 2019Selenium-Modified Microgels as Bio-Inspired Oxidation Catalystscitations
- 2019Heterolepic β-Ketoiminate Zinc Phenoxide Complexes as Efficient Catalysts for the Ring Opening Polymerization of Lactidecitations
- 2019Heterolepic β‐Ketoiminate Zinc Phenoxide Complexes as Efficient Catalysts for the Ring Opening Polymerization of Lactide
- 2019Tuning Channel Architecture of Interdigitated Organic Electrochemical Transistors for Recording the Action Potentials of Electrogenic Cellscitations
- 2017Internal structure and phase transition behavior of stimuli-responsive microgels in PEG meltscitations
- 2014Water dispersible electrically conductive poly(3,4- ethylenedioxythiophene) nanospindles by liquid crystalline template assisted polymerizationcitations
- 2013Formation of catalytically active gold-polymer microgel hybrids via a controlled in situ reductive processcitations
Places of action
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article
Dual-Temperature-Responsive Microgels from a Zwitterionic Functional Graft Copolymer with Superior Protein Repelling Property
Abstract
<p>In this work, we developed a synthetic strategy to synthesize dual-temperature-responsive low surface fouling zwitterionic microgels. Statistical poly(N-vinylcaprolactam-co-glycidyl methacrylate) copolymers were synthesized by RAFT polymerization and post-modified by thiol-epoxy click reaction with thiol end-group-modified poly(sulfobetaine) macro-RAFT (PSB-SH) to obtain poly(N-vinylcaprolactam-co-glycidyl methacrylate)-graft-poly(sulfobetaine) (PVCL-co-PGMA-g-PSB) graft copolymers. Synthesized graft copolymers were cross-linked by diamine cross-linker in water-in-oil (w/o) inverse mini-emulsion to obtain zwitterionic microgels. Using this approach, we synthesized microgels with unique microstructure, high loading and uniform distribution of poly(sulfobetaine) chains, which exhibits tunable dual-volume phase transition temperatures. The microgels also showed excellent antifouling property reflected in strongly reduced protein absorption on a microgel-coated surface observed in real time by a Quartz Crystal Microbalance with Dissipation (QCM-D) monitoring experiment with continuous flow of protein solution. Therefore, this kind of zwitterionic microgel can be potentially used for temperature-triggered drug delivery and anti-bioadhesion coating material as well.</p>