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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Koster, Lja
University of Groningen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (32/32 displayed)
- 2023The Role of Thermalization in the Cooling Dynamics of Hot Carrier Solar Cellscitations
- 2022A method for identifying the cause of inefficient salt-doping in organic semiconductorscitations
- 2022Vacuum-Deposited Cesium Tin Iodide Thin Films with Tunable Thermoelectric Propertiescitations
- 2022Backbone-driven host-dopant miscibility modulates molecular doping in NDI conjugated polymerscitations
- 2021Amphipathic Side Chain of a Conjugated Polymer Optimizes Dopant Location toward Efficient N-Type Organic Thermoelectricscitations
- 2021Revealing Charge Carrier Mobility and Defect Densities in Metal Halide Perovskites via Space-Charge-Limited Current Measurementscitations
- 2021Understanding Dark Current-Voltage Characteristics in Metal-Halide Perovskite Single Crystalscitations
- 2021Carrier-carrier Coulomb interactions reduce power factor in organic thermoelectricscitations
- 2021Molecular Doping Directed by a Neutral Radicalcitations
- 2020Reaching a Double-Digit Dielectric Constant with Fullerene Derivativescitations
- 2020Electrical Conductivity of Doped Organic Semiconductors Limited by Carrier-Carrier Interactionscitations
- 2020N-type organic thermoelectricscitations
- 2020Toward Understanding Space-Charge Limited Current Measurements on Metal Halide Perovskitescitations
- 20191,8-diiodooctane acts as a photo-acid in organic solar cellscitations
- 2018Enhanced n-Doping Efficiency of a Naphthalenediimide-Based Copolymer through Polar Side Chains for Organic Thermoelectricscitations
- 2017N-Type Organic Thermoelectricscitations
- 2017Relating polymer chemical structure to the stability of polymer:citations
- 2016Deposition of LiF onto Films of Fullerene Derivatives Leads to Bulk Dopingcitations
- 2016N-type polymers as electron extraction layers in hybrid perovskite solar cells with improved ambient stabilitycitations
- 2016A New Figure of Merit for Organic Solar Cells with Transport-limited Photocurrentscitations
- 2016Compatibility of PTB7 and [70]PCBM as a Key Factor for the Stability of PTB7citations
- 2015The Effect of Large Compositional Inhomogeneities on the Performance of Organic Solar Cellscitations
- 2015Strategy for Enhancing the Dielectric Constant of Organic Semiconductors Without Sacrificing Charge Carrier Mobility and Solubilitycitations
- 2014Strategy for Enhancing the Electric Permittivity of Organic Semiconductors
- 2014Charge transport and recombination in PDPP5Tcitations
- 2011Validity of the Einstein Relation in Disordered Organic Semiconductorscitations
- 2007Device physics of polymercitations
- 2007Device physics of donor/acceptor-blend solar cells
- 2007Hybrid polymer solar cells from highly reactive diethylzinccitations
- 2006Light intensity dependence of open-circuit voltage and short-circuit current of polymer/fullerene solar cellscitations
- 2005Origin of the light intensity dependence of the short-circuit current of polymer/fullerene solar cellscitations
- 2004Effect of metal electrodes on the performance of polymercitations
Places of action
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article
Toward Understanding Space-Charge Limited Current Measurements on Metal Halide Perovskites
Abstract
<p>Metal halide perovskite semiconductors have sprung to the forefront of research into optoelectronic devices and materials, largely because of their remarkable photovoltaic efficiency records above 25% in single-junction devices and 28% in tandem solar cells, achieved within a decade of research. Despite this rapid progress, ionic conduction within the semiconductor still puzzles the community and can have a significant impact on all metal halide perovskite-based optoelectronic devices because of its influence upon electronic and optoelectronic processes. This phenomenon thus also makes the interpretation of electrical characterization techniques, which probe the fundamental properties of these materials, delicate and complex. For example, space-charge limited current measurements are widely used to probe defect densities and carrier mobilities in perovskites. However, the influence of mobile ions upon these measurements is significant but has yet to be considered. Here we report the effect of mobile ions upon electronic conductivity during space-charge limited current measurements of MAPbBr<sub>3</sub> single crystals and show that conventional interpretations deliver erroneous results. We introduce a pulsed-voltage space-charge limited current procedure to achieve reproducible current-voltage characteristics without hysteresis. From this revised pulsed current-voltage sweep, we elucidate a lower bound trap-density value of 2.8 ± 1.8 × 10<sup>12</sup> cm<sup>-3</sup> in MAPbBr<sub>3</sub> single crystals. This work will lead to more accurate characterization of halide perovskite semiconductors and ultimately more effective device optimization.</p>