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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Munir, Rahim
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2022An open-access database and analysis tool for perovskite solar cells based on the FAIR data principlescitations
- 2021An open-access database and analysis tool for perovskite solar cells based on the FAIR data principlescitations
- 2021Compositional and Interfacial Engineering Yield High-Performance and Stable p-i-n Perovskite Solar Cells and Mini-Modulescitations
- 2020Hybrid perovskite crystallization from binary solvent mixtures: interplay of evaporation rate and binding strength of solventscitations
- 2019Lattice anchoring stabilizes solution-processed semiconductorscitations
- 2017Programmable and coherent crystallization of semiconductors.citations
- 2017Enhanced Electrical Conductivity of Molecularly p-Doped Poly(3-hexylthiophene) through Understanding the Correlation with Solid-State Ordercitations
- 2017Hybrid perovskite solar cells: In situ investigation of solution-processed PbI2 reveals metastable precursors and a pathway to producing porous thin filmscitations
- 2017Enhanced Electrical Conductivity of Molecularly p-Doped Poly(3-hexylthiophene) through Understanding the Correlation with Solid-State Order.citations
- 2016Solution-processable MoO x nanocrystals enable highly efficient reflective and semitransparent polymer solar cellscitations
- 2016Solution-processable MoOx nanocrystals enable highly efficient reflective and semitransparent polymer solar cellscitations
- 2016Mesostructured Fullerene Electrodes for Highly Efficient n–i–p Perovskite Solar Cellscitations
- 2016Hybrid Perovskite Thin-Film Photovoltaics: In Situ Diagnostics and Importance of the Precursor Solvate Phasescitations
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article
Mesostructured Fullerene Electrodes for Highly Efficient n–i–p Perovskite Solar Cells
Abstract
Electron-transporting layers in today’s state-of-the-art n–i–p organohalide perovskite solar cells are almost exclusively made of metal oxides. Here, we demonstrate a novel mesostructured fullerene-based electron-transporting material (ETM) that is crystalline, hydrophobic, and cross-linked, rendering it solvent- and heat-resistant for subsequent perovskite solar cell fabrication. The fullerene ETM is shown to enhance the structural and electronic properties of the CH3NH3PbI3 layer grown atop, reducing its Urbach energy from ∼26 to 21 meV, while also increasing crystallite size and improving texture. The resulting mesostructured n–i–p solar cells achieve reduced recombination, improved device-to-device variation, reduced hysteresis, and a power conversion efficiency above 15%, surpassing the performance of similar devices prepared using mesoporous TiO2 and well above the performance of planar heterojunction devices on amorphous or crystalline [6,6]-phenyl-C61-butyric acid methyl ester (PCBM). This work is...