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Naji, M. |
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Motta, Antonella |
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Taccardi, Nicola |
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Casati, R. |
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Ali, M. A. |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Li, Peng
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Publications (6/6 displayed)
- 2024Strain Heterogeneity and Extended Defects in Halide Perovskite Devicescitations
- 2024Strain Heterogeneity and Extended Defects in Halide Perovskite Devices.
- 2015Spray-coated epoxy barrier films containing high aspect ratio functionalized graphene nanosheetscitations
- 2015Is NiCo2S4 really a semiconductor?citations
- 2014Generation of pure spin currents via spin Seebeck effect in self-biased hexagonal ferrite thin filmscitations
- 2011Structural Disorder in Doped Zirconias, Part I: The Zr0.8Sc0.2-xYxO1.9 (0.0 Systemcitations
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article
Strain Heterogeneity and Extended Defects in Halide Perovskite Devices
Abstract
Strain is an important property in halide perovskite semiconductors used for optoelectronic applications because of its ability to influence device efficiency and stability. However, descriptions of strain in these materials are generally limited to bulk averages of bare films, which miss important property-determining heterogeneities that occur on the nanoscale and at interfaces in multilayer device stacks. Here, we present three-dimensional nanoscale strain mapping using Bragg coherent diffraction imaging of individual grains in Cs0.1FA0.9Pb(I0.95Br0.05)3 and Cs0.15FA0.85SnI3 (FA = formamidinium) halide perovskite absorbers buried in full solar cell devices. We discover large local strains and striking intragrain and grain-to-grain strain heterogeneity, identifying distinct islands of tensile and compressive strain inside grains. Additionally, we directly image dislocations with surprising regularity in Cs0.15FA0.85SnI3 grains and find evidence for dislocation-induced antiphase boundary formation. Our results shine a rare light on the nanoscale strains in these materials in their technologically relevant device setting.