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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Tekelenburg, Eelco K.
University of Groningen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Cation Influence on Hot-Carrier Relaxation in Tin Triiodide Perovskite Thin Filmscitations
- 2024Quasi-2D Lead–Tin Perovskite Memory Devices Fabricated by Blade Coatingcitations
- 2024Mechanism of Hot-Carrier Photoluminescence in Sn-Based Perovskitescitations
- 2024Metal-Solvent Complex Formation at the Surface of InP Colloidal Quantum Dotscitations
- 2023The Origin of Broad Emission in ⟨100⟩ Two-Dimensional Perovskites: Extrinsic vs Intrinsic Processes.
- 2023The Origin of Broad Emission in ⟨100⟩ Two-Dimensional Perovskites: Extrinsic vs Intrinsic Processes.
- 2023Unraveling the Broadband Emission in Mixed Tin-Lead Layered Perovskitescitations
- 2023Unraveling the Broadband Emission in Mixed Tin-Lead Layered Perovskitescitations
- 2023Impact of two diammonium cations on the structure and photophysics of layered Sn-based perovskitescitations
- 2022The Origin of Broad Emission in ⟨100⟩ Two-Dimensional Perovskites: Extrinsic vs Intrinsic Processes.
- 2022The Origin of Broad Emission in ⟨100⟩ Two-Dimensional Perovskites: Extrinsic vs Intrinsic Processescitations
- 2022The Origin of Broad Emission in ⟨100»Two-Dimensional Perovskites:Extrinsic vs Intrinsic Processescitations
- 2022The Origin of Broad Emission in â ¨100»Two-Dimensional Perovskites: Extrinsic vs Intrinsic Processes
- 2020Extrinsic nature of the broad photoluminescence in lead iodide-based Ruddlesden-Popper perovskitescitations
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article
Cation Influence on Hot-Carrier Relaxation in Tin Triiodide Perovskite Thin Films
Abstract
Slow hot-carrier cooling may potentially allow overcoming the maximum achievable power conversion efficiency of single-junction solar cells. For formamidinium tin triiodide, an exceptional slow cooling time of a few nanoseconds was reported. However, a systematic study of the cation influence, as is present for lead compounds, is lacking. Here, we report the first comparative study on formamidinium, methylammonium, and cesium tin triiodide thin films. By investigating their photoluminescence, we observe a considerable shift of the emission peak to high energy with the increase of the excited-state population, which is more prominent in the case of the two hybrid organic-inorganic perovskites (∼45 meV vs ∼15 meV at 9 × 10 17 cm -3 carrier density). The hot-carrier photoluminescence of the three tin compositions decays with a 0.6-2.8 ns time constant with slower cooling observed for the two hybrids, further indicating their importance.