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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Duim, Herman
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (25/25 displayed)
- 2023Disentangling Dual Emission Dynamics in Lead Bromide Perovskitecitations
- 2023Disentangling Dual Emission Dynamics in Lead Bromide Perovskitecitations
- 2023Addition of Ammonium Thiocyanate Alters the Microstructure and Energetic Landscape of 2D/3D Perovskite Films
- 2022Taking a closer look - how the microstructure of Dion-Jacobson perovskites governs their photophysics.
- 2022Metal Halide Perovskites
- 2022Taking a closer look - how the microstructure of Dion-Jacobson perovskites governs their photophysicscitations
- 2021Photophysics of Two-Dimensional Perovskites—Learning from Metal Halide Substitutioncitations
- 2021Photophysics of Two-Dimensional Perovskites—Learning from Metal Halide Substitution
- 2021Brightening of dark excitons in 2D perovskitescitations
- 2021Scalable, Template Driven Formation of Highly Crystalline Lead-Tin Halide Perovskite Filmscitations
- 2021Scalable, Template Driven Formation of Highly Crystalline Lead-Tin Halide Perovskite Filmscitations
- 2020Broad Tunability of Carrier Effective Masses in Two-Dimensional Halide Perovskitescitations
- 2020Unraveling the Microstructure of Layered Metal Halide Perovskite Filmscitations
- 2020Unraveling the Microstructure of Layered Metal Halide Perovskite Filmscitations
- 2020Extrinsic nature of the broad photoluminescence in lead iodide-based Ruddlesden-Popper perovskitescitations
- 2020Stable cesium formamidinium lead halide perovskites: a comparison of photophysics and phase purity in thin films and single crystalscitations
- 2019Stable Cesium Formamidinium Lead Halide Perovskitescitations
- 2019Mechanism of surface passivation of methylammonium lead tribromide single crystals by benzylaminecitations
- 2019Mechanism of surface passivation of methylammonium lead tribromide single crystals by benzylaminecitations
- 2019Enhancing the crystallinity and perfecting the orientation of formamidinium tin iodide for highly efficient Sn-based perovskite solar cellscitations
- 2019Scalable fabrication of high-quality crystalline and stable FAPbI(3) thin films by combining doctor-blade coating and the cation exchange reactioncitations
- 2019Scalable fabrication of high-quality crystalline and stable FAPbI(3) thin films by combining doctor-blade coating and the cation exchange reactioncitations
- 2019The Impact of Stoichiometry on the Photophysical Properties of Ruddlesden-Popper Perovskitescitations
- 2019Stable Cesium Formamidinium Lead Halide Perovskites:A Comparison of Photophysics and Phase Purity in Thin Films and Single Crystalscitations
- 2019Effects of strontium doping on the morphological, structural, and photophysical properties of FASnI(3) perovskite thin filmscitations
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article
Broad Tunability of Carrier Effective Masses in Two-Dimensional Halide Perovskites
Abstract
The effective mass of charge carriers is a crucial parameter for the design of any optoelectronic device. The estimated values of the effective mass of 2D halide perovskites currently span a broad range, providing an unwelcome source of confusion in this promising material system. Here we highlight how the distortion imposed by the organic spacers, and orbital hybridization effects by the metal cation, govern the effective mass. As a result, the effective mass in 2D halide perovskites can be easily tailored over a wide range. To demonstrate this, we have directly measured the reduced effective mass of charge carriers in phenethylamine (PEA)-based 2D halide perovskites. Combining the experimental results with electronic band-structure calculations, we propose a scaling diagram for the effective mass value versus the distortion of the octahedra imposed by the organic cations.