| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Amal, Rose
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024Triggering C‒N Coupling on Metal Oxide Nanocomposite for the Electrochemical Reduction of CO<sub>2</sub> and NO<i><sub>x</sub></i>⁻ to Formamidecitations
- 2021Integrating low-cost earth-abundant co-catalysts with encapsulated perovskite solar cells for efficient and stable overall solar water splittingcitations
- 2020Dynamic single-site polysulfide immobilization in long-range disorder Cu-MOFscitations
- 2020Tuning the Selectivity of LaNiO3 Perovskites for CO2 Hydrogenation through Potassium Substitutioncitations
- 2018Multipronged Validation of Oxalate C-C Bond Cleavage Driven by Au-TiO2 Interfacial Charge Transfer Using Operando DRIFTScitations
- 2018Electroreduction of CO2 to CO on a Mesoporous Carbon Catalyst with Progressively Removed Nitrogen Moietiescitations
- 2016Photoelectrochemical water oxidation using a Bi2MoO6/MoO3 heterojunction photoanode synthesised by hydrothermal treatment of an anodised MoO3 thin filmcitations
- 2015Z-schematic water splitting into H2 and O2 using metal sulfide as a hydrogen-evolving photocatalyst and reduced graphene oxide as a solid-state electron mediatorcitations
- 2014Interface-dependent electrochemical behavior of nanostructured manganese (IV) oxide (Mn3O4)citations
- 2012A perspective on fabricating carbon-based nanomaterials by photocatalysis and their applicationscitations
- 2011Semiconductor/reduced graphene oxide nanocomposites derived from photocatalytic reactionscitations
Places of action
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article
Multipronged Validation of Oxalate C-C Bond Cleavage Driven by Au-TiO2 Interfacial Charge Transfer Using Operando DRIFTS
Abstract
We devised a multipronged approach to validate the mechanism of oxalate C-C bond cleavage and the role of Au/TiO<sub>2</sub> interfacial interaction via (i) selective photodriven electronic transfer and (ii) tempering of the electronic interaction by alloying Au with Cu, which serves as an electron sink. This approach allows us to speed up, slow down, impede, and bypass the interfacial electronic transfer. The multipronged approach led to a singular conclusion: Au-TiO<sub>2</sub> electronic interaction played a critical role in C-C bond cleavage by fixating bidentate oxalate species at the Au-TiO<sub>2</sub> interfacial perimeter with parallel C-C bonds to the TiO<sub>2</sub> surface.