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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Plana, Daniela
Keele University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2017Real-Time Tracking of Metal Nucleation via Local Perturbation of Hydration Layerscitations
- 2016A Synthetic Route for the Effective Preparation of Metal Alloy Nanoparticles and Their Use as Active Electrocatalystscitations
- 2015Surface Activation of Pt Nanoparticles Synthesised by "Hot Injection" in the Presence of Oleylaminecitations
- 2015Growth of Epitaxial Pt<inf>1-x</inf>Pb<inf>x</inf> Alloys by Surface Limited Redox Replacement and Study of Their Adsorption Propertiescitations
- 2013Electrochemical crystallization of spatially organized copper microwire arrays within biomineralized (dentine) templatescitations
- 2012Electrocatalytic Properties of Strained Pd Nanoshells at Au Nanostructures: CO and HCOOH Oxidationcitations
Places of action
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article
A Synthetic Route for the Effective Preparation of Metal Alloy Nanoparticles and Their Use as Active Electrocatalysts
Abstract
By taking advantage of the nonequilibrium synthetic conditions, we used the cathodic corrosion method to prepare a selected number of alloys of which solid-solution alloys do not exist under ambient conditions. To illustrate our findings, we present the preparation at room temperature of PtBi and PtPb alloy nanoparticles with various compositions. These alloys have shown benchmark mass activity and durability with respect to formic acid oxidation. The improvement in the catalytic activity is explained on the basis of the composition of the metal alloys, the reduced particle size, and, quite importantly, the level of cleanliness of the catalyst obtained by this method.