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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Shiddiky, Muhammad J. A.
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Topics
Publications (12/12 displayed)
- 2020Electropolymerized porous polymer films on flexible indium tin oxide using trifunctional furan substituted benzene conjugated monomer for biosensingcitations
- 2019Naphthalene flanked diketopyrrolopyrrolecitations
- 2018Robust free-standing nano-thin SiC membranes enable direct photolithography for MEMS sensing applicationscitations
- 2018Graphene-oxide-loaded superparamagnetic iron oxide nanoparticles for ultrasensitive electrocatalytic detection of microRNAcitations
- 2017Self-assembly of polymeric micelles made of asymmetric polystyrene-b-polyacrylic acid-b-polyethylene oxide for the synthesis of mesoporous nickel ferritecitations
- 2016Cyano-Bridged Trimetallic Coordination Polymer Nanoparticles and Their Thermal Decomposition into Nanoporous Spinel Ferromagnetic Oxidescitations
- 2016Biosensing made easy with PEG-targeted bi-specific antibodiescitations
- 2015Conditions Favoring the Formation of Monomeric PtIII Derivatives in the Electrochemical Oxidation of trans-[PtII{(p-BrC6F4)NCH2CH2NEt2}Cl(py)]citations
- 2013"Drill and fill" lithography for controlled fabrication of 3D platinum electrodescitations
- 2012Fabrication and characterization of gold nanohole electrode arrayscitations
- 2008Fabrication of disposable sensors for biomolecule detection using hydrazine electrocatalystcitations
- 2007Hydrazine-catalyzed ultrasensitive detection of DNA and proteinscitations
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article
Electropolymerized porous polymer films on flexible indium tin oxide using trifunctional furan substituted benzene conjugated monomer for biosensing
Abstract
In recent years, conducting polymers are playing a significant role in the field of display devices, transistors, solar cells, sensors, and electrochromic windows due to their outstanding optoelectronic and semiconducting properties due to their conjugated backbone. One potential application that is not as widely explored using these materials is biosensing, where advantage is taken of the porosity that can be generated by the polymerization of a three-dimensional network. There are various approaches for producing conjugated microporous polymers using trifunctional or multifunctional monomers synthesized via chemical or electrochemical methods. In this work, we have used electropolymerization to synthesize conjugated polymer films on a working electrode of flexible indium tin oxide (FITO) using a trifunctional conjugated monomer 1,3,5-tri(furan-2-yl)benzene (TFB). There are several parameters that influence the formation of a porous polymer film, and the most critical ones are substrate conductivity, roughness, method of electropolymerization, and choice of an electrolyte. These porous electropolymerized films were characterized using UV-vis spectroscopy (UV-vis), X-ray photoelectron spectroscopy (XPS), surface profilometry, four-point probe conductivity measurements, and scanning electron microscopy (SEM). The polymer films that were electropolymerized using chronoamperometry rather than repetitive potential cycling demonstrated a more suitable morphology to trap DNA/RNA analytes for biosensing applications.