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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Petrov, R. H. | Madrid |
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Casati, R. |
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Kočí, Jan | Prague |
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Azam, Siraj |
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Blanpain, Bart |
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Ali, M. A. |
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Rančić, M. |
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Azevedo, Nuno Monteiro |
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article
Polyphosphazene-Tannic Acid Colloids as Building Blocks for Bio-Based Flame-Retardant Coatings
Abstract
<p>Colloids using hexachlorocyclophosphazene (HCCP) and natural polyphenol tannic acid (TA) were synthesized for the first time under precipitation polycondensation conditions. The synthesis parameters were optimized to obtain submicrometer cross-linked polymer colloids with variable TA/HCCP ratios. Using thermogravimetric analysis coupled with FTIR spectroscopy, we demonstrate that TA/HCCP particles exhibit high thermal stability and high char-forming ability. Synthesized polymer colloids can be easily redispersed in water, forming colloidally stable dispersions as confirmed by dynamic light scattering. Aqueous formulations of TA/HCCP particles were used to coat cotton samples. TA/HCCP coatings exhibit excellent flame-retardant properties with a maximal limiting oxygen index (LOI) of 35.</p>