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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Cseri, Levente
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Tunable 2D Conjugated Porous Organic Polymer Films for Precise Molecular Nanofiltration and Optoelectronicscitations
- 2021Electrospun Adsorptive Nanofibrous Membranes from Ion Exchange Polymers to Snare Textile Dyes from Wastewatercitations
- 2021Electrospun Adsorptive Nanofibrous Membranes from Ion Exchange Polymers to Snare Textile Dyes from Wastewatercitations
- 2020Metal–Organic Frameworks (MOFs) and MOF-Derived Porous Carbon Materials for Sustainable Adsorptive Wastewater Treatment
- 2020Asymmetric Membrane Capacitive Deionization using Anion-Exchange Membranes based on Quaternized Polymer Blendscitations
- 2020Asymmetric Membrane Capacitive Deionization using Anion-Exchange Membranes based on Quaternized Polymer Blendscitations
- 2020Graphene–PSS/L-DOPA nanocomposite cation exchange membranes for electrodialysis desalinationcitations
- 2020Graphene–PSS/L-DOPA nanocomposite cation exchange membranes for electrodialysis desalinationcitations
- 2019Electrostatically-coupled graphene oxide nanocomposite cation exchange membranecitations
- 2019Electrostatically-coupled graphene oxide nanocomposite cation exchange membranecitations
- 2018Robust Covalently Crosslinked Polybenzimidazole/Graphene Oxide Membranes for High-Flux Organic Solvent Nanofiltrationcitations
- 2018Graphene oxide – polybenzimidazolium nanocomposite anion exchange membranes for electrodialysiscitations
- 2018Graphene oxide – polybenzimidazolium nanocomposite anion exchange membranes for electrodialysiscitations
- 2018Robust Covalently Cross-linked Polybenzimidazole/Graphene Oxide Membranes for High-Flux Organic Solvent Nanofiltrationcitations
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article
Asymmetric Membrane Capacitive Deionization using Anion-Exchange Membranes based on Quaternized Polymer Blends
Abstract
Membrane capacitive deionization (MCDI) for water desalination is an innovative technique that could help to solve the global water scarcity problem. However, the development of the MCDI field is hindered by the limited choice of ion-exchange membranes. Desalination by MCDI removes the salt (solute) from the water (solvent); which can drastically reduce energy consumption compared to traditional desalination practices such as distillation. Herein, we outline the fabrication and characterization of quaternized anion-exchange membranes (AEMs) based on polymer blends of polyethylenimine (PEI) and polybenzimidazole (PBI) that provides an efficient membrane for MCDI. Flat sheet polymer membranes were prepared by solution casting, heat treatment and phase inversion, followed by modification to impart anion-exchange character. Scanning electron microscopy (SEM), atomic force microscopy (AFM), nuclear magnetic resonance (NMR) and Fourier-Transform infrared (FTIR) spectroscopy were used to characterize the morphology and chemical composition of the membranes. The as-prepared membranes displayed high ion-exchange capacity (IEC), hydrophilicity, permselectivity and low area resistance. Due to the addition of PEI, the high density of quaternary ammonium groups increased the IEC and permselectivity of the membranes, while reducing the area resistance relative to pristine PBI AEMs. Our PEI/PBI membranes were successfully employed in asymmetric MCDI for brackish water desalination and exhibited an increase in both salt adsorption capacity (>3x) and charge efficiency (>2x) relative to membrane-free CDI. The use of quaternized polymer blend membranes could help to achieve the greater realization of industrial scale MCDI.