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Appiah, Clement
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article
Mechanochromic Microfibers Stabilized by Polymer Blending
Abstract
Stimuli-responsive polymers processed into microfibers bear the potential to be fabricated as systems detecting stress-induced failures. Microfiber processing of spiropyran (SP)-functionalized polymer poly(methyl acrylate) (PMA), in pristine form and as a blend with poly(methyl methacrylate) (PMMA), was studied. Material inhomogeneities such as bead formation and fiber-fiber fusion affected the durability of the microfibers which were aimed to be applied as self-reporting materials. The present study investigates the effect of polymer blending to improve the structural stability, i.e., the shape of the fibers compared to the nonblended PMA fibers (NBF). Blended microfibers (BF) with