People | Locations | Statistics |
---|---|---|
Naji, M. |
| |
Motta, Antonella |
| |
Aletan, Dirar |
| |
Mohamed, Tarek |
| |
Ertürk, Emre |
| |
Taccardi, Nicola |
| |
Kononenko, Denys |
| |
Petrov, R. H. | Madrid |
|
Alshaaer, Mazen | Brussels |
|
Bih, L. |
| |
Casati, R. |
| |
Muller, Hermance |
| |
Kočí, Jan | Prague |
|
Šuljagić, Marija |
| |
Kalteremidou, Kalliopi-Artemi | Brussels |
|
Azam, Siraj |
| |
Ospanova, Alyiya |
| |
Blanpain, Bart |
| |
Ali, M. A. |
| |
Popa, V. |
| |
Rančić, M. |
| |
Ollier, Nadège |
| |
Azevedo, Nuno Monteiro |
| |
Landes, Michael |
| |
Rignanese, Gian-Marco |
|
Murzin, Dmitry Yu
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2023Interactions between Iron and Nickel in Fe-Ni Nanoparticles on Y Zeolite for Co-Processing of Fossil Feedstock with Lignin-Derived Isoeugenolcitations
- 2023Dry Reforming of Methane over Ni-Fe-Al Catalysts Prepared by Solution Combustion Synthesiscitations
- 2022CuZSM-5@HMS composite as an efficient micro-mesoporous catalyst for conversion of sugars into levulinic acidcitations
- 2022Catalyst supports based on ZnO-ZnAl 2 O 4 nanocomposites with enhanced selectivity and coking resistance in isobutane dehydrogenationcitations
- 2021Effect of metal particle shape on hydrogen assisted reactionscitations
- 2021Mono- and Bimetallic Ni−Co Catalysts in Dry Reforming of Methanecitations
- 2021Mono‐ and Bimetallic Ni−Co Catalysts in Dry Reforming of Methanecitations
- 2020Transformation of industrial steel slag with different structure-modifying agents for synthesis of catalystscitations
- 2019Synthesis and Characterization of Novel Catalytic Materials Using Industrial Slag:Influence of Alkaline Pretreatment, Synthesis Time and Temperaturecitations
- 2019Synthesis and Characterization of Novel Catalytic Materials Using Industrial Slagcitations
- 2016Alumina ceramic foams as catalyst supportscitations
- 2013Imidazolium-Based Poly(ionic liquid)s as New Alternatives for CO2 Capture.citations
- 2010Decarboxylation of fatty acids over Pd supported on mesoporous carboncitations
- 2008Synthesis of biodiesel via deoxygenation of stearic acid over supported Pd/C catalystcitations
Places of action
Organizations | Location | People |
---|
article
Interactions between Iron and Nickel in Fe-Ni Nanoparticles on Y Zeolite for Co-Processing of Fossil Feedstock with Lignin-Derived Isoeugenol
Abstract
<p>A set of low-cost monometallic Fe, Ni, and bimetallic Fe-Ni bifunctional H-Y-5.1 catalysts with different metal ratios were synthesized by sequential incipient wetness impregnation. The catalysts were characterized in detail by N<sub>2</sub> physisorption, Fourier transform infrared spectroscopy with pyridine, inductively coupled plasma optical emission spectroscopy, X-ray diffraction (XRD), transmission and scanning electron microscopy (TEM-SEM), magic angle spinning nuclear magnetic resonance, X-ray photoelectron spectroscopy (XPS), Mössbauer spectroscopy, magnetic measurements, temperature-programmed reduction (TPR), and X-ray absorption spectroscopy (XAS). The results revealed that introduction of Fe led to a decrease of strong acid sites and an increase of medium Brønsted acid sites, while introduction of Ni increased the number of Lewis acid sites. The particle size of iron was approx. 5 nm, being ca. fourfold higher for nickel. XPS demonstrated higher iron content on the catalyst surface compared to nickel. Both Mössbauer spectroscopy and magnetic measurement confirmed the ferromagnetic behavior of all catalysts. In addition, the results from XRD, TEM, XPS, XAS, and magnetization suggested strong Fe-Ni nanoparticle interactions, which were supported by modeling of TPR profiles. Catalytic results of the co-processing of fossil feedstock with lignin-derived isoeugenol clearly showed that both product distribution and activity of Fe-Ni catalysts strongly depend on the metals’ ratio and their interactions. Key properties affected by the Fe-Ni metal ratio, which played a positive role in co-processing, were a smaller medial metal nanoparticle size (<6 nm), a lower metal-acid site ratio, as well as presence in the catalyst of fcc FeNi alloy structure and fcc Ni doped with Fe.</p>