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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Huijben, Mark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2022Self-Assembled Epitaxial Cathode-Electrolyte Nanocomposites for 3D Microbatteriescitations
- 2021Lithium-based vertically aligned nanocomposites for three-dimensional solid-state batteriescitations
- 2020Tailoring Vanadium Dioxide Film Orientation Using Nanosheets: a Combined Microscopy, Diffraction, Transport, and Soft X‐Ray in Transmission Studycitations
- 2020Tailoring Vanadium Dioxide Film Orientation Using Nanosheets: a Combined Microscopy, Diffraction, Transport, and Soft X‐Ray in Transmission Studycitations
- 2020Tailoring Vanadium Dioxide Film Orientation Using Nanosheets : a Combined Microscopy, Diffraction, Transport, and Soft X-Ray in Transmission Studycitations
- 2019Morphology Evolution during Lithium-Based Vertically Aligned Nanocomposite Growthcitations
- 2016Long-range domain structure and symmetry engineering by interfacial oxygen octahedral coupling at heterostructure interfacecitations
- 2012High-Temperature Magnetic Insulating Phase in Ultrathin La0.67Sr0.33MnO3 Filmscitations
- 2010Suppression of Octahedral Tilts and Associated Changes in Electronic Properties at Epitaxial Oxide Heterostructure Interfaces
- 2007Magnetic effects at the interface between non-magnetic oxidescitations
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article
Morphology Evolution during Lithium-Based Vertically Aligned Nanocomposite Growth
Abstract
<p>Ceramic-based nanocomposites are a rapidly evolving research area as they are currently being used in a wide range of applications. Epitaxial vertically aligned nanocomposites (VANs) offer promising advantages over conventional planar multilayers as key functionalities are tailored by the strong coupling at their vertical interfaces. However, limited knowledge exists of which material systems are compatible in composite films and which types of structures are optimal for a given functionality. No lithium-based VANs have yet been explored for energy storage, while 3D solid-state batteries offer great promise for enhanced energy and power densities. Although solid-on-solid kinetic Monte Carlo simulation (KMCS) models of VAN growth have previously been developed, phase separation was forced into the systems by limiting hopping directions and/or tuning the activation energies for hopping. Here, we study the influence of the temperature and deposition rate on the morphology evolution of lithium-based VANs, consisting of a promising LiMn<sub>2</sub>O<sub>4</sub> cathode and a Li<sub>0.5</sub>La<sub>0.5</sub>TiO<sub>3</sub> electrolyte, by applying a KMCS model with activation energies for hopping obtained experimentally and with minimum restrictions for hopping directions. Although the model considers only the kinetic processes away from thermodynamic equilibrium, which would determine the final shape of the pillars within the matrix, the trends in pillar size and distribution within the simulated VANs are in good agreement with experiments. This provides an elegant tool to predict the growth of VAN materials as the experimental activation energies and higher degrees of freedom for hopping result in a more realistic and low computational cost model to obtain accurate simulations of VAN materials.</p>