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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ackermann, Jörg
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (22/22 displayed)
- 2024Ternary Polymer Solar Cells: Impact of Non-Fullerene Acceptors on Optical and Morphological Propertiescitations
- 2023Star-shape non-fullerene acceptor featuring an aza-triangulene core for organic solar cellscitations
- 2023Star-shape non-fullerene acceptor featuring an aza-triangulene core for organic solar cellscitations
- 2023Towards efficient NFA-based selective near-infrared organic photodetectors: impact of thermal annealing of polymer blendscitations
- 2022Improved ultraviolet stability of fullerene-based organic solar cells through light-induced enlargement and crystallization of fullerene domainscitations
- 2022Synthesis and Electron Accepting Properties of Two Di(benz[f]indenone)-Fused Tetraazaanthracene Isomerscitations
- 2022High-Efficiency Digital Inkjet-Printed Non-Fullerene Polymer Blends Using Non-Halogenated Solventscitations
- 2020Robust transparent conducting electrode based on silver nanowire coating on polyelectrolytes multilayerscitations
- 2019A new antimony-based organic-inorganic hybrid material as electron extraction layer for efficient and stable polymer solar cellscitations
- 2019A new antimony-based organic-inorganic hybrid material as electron extraction layer for efficient and stable polymer solar cellscitations
- 2017P-type semiconductor surfactant modified zinc oxide nanorods for hybrid bulk heterojunction solar cellscitations
- 2017Toward High-Temperature Stability of PTB7-Based Bulk Heterojunction Solar Cells: Impact of Fullerene Size and Solvent Additivecitations
- 2017Toward High-Temperature Stability of PTB7-Based Bulk Heterojunction Solar Cells: Impact of Fullerene Size and Solvent Additivecitations
- 2016Effect of ZnO nanoparticles on the photochemical and electronic stability of P3HT used in polymer solar cellscitations
- 2016Effect of ZnO nanoparticles on the photochemical and electronic stability of P3HT used in polymer solar cellscitations
- 2016Insight about electrical properties of low-temperature solution-processed Al-doped ZnO nanoparticle based layers for TFT applicationscitations
- 2016Insight about electrical properties of low-temperature solution-processed Al-doped ZnO nanoparticle based layers for TFT applicationscitations
- 2016Ligand-Free Synthesis of Aluminum-Doped Zinc Oxide Nanocrystals and their Use as Optical Spacers in Color-Tuned Highly Efficient Organic Solar Cellscitations
- 2016Ligand-Free Synthesis of Aluminum-Doped Zinc Oxide Nanocrystals and their Use as Optical Spacers in Color-Tuned Highly Efficient Organic Solar Cellscitations
- 2016Ligand-free synthesis of aluminum-doped zinc oxide nanocrystals and their use as optical spacers in color-tuned highly efficient organic solar cellscitations
- 2013A star-shaped molecule as hole transporting material in solution-processed thin-film transistorscitations
- 2012A New Active Organic Component for Flexible Ammonia Gas Sensorscitations
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article
A new antimony-based organic-inorganic hybrid material as electron extraction layer for efficient and stable polymer solar cells
Abstract
Hybrid organic-inorganic materials are a new class of material used as interfacial layers in polymer solar cells. A hybrid material, composed of antimony as inorganic part and diaminopyridine as organic part, is synthesized and described as a new material for electron extraction layer in polymer solar cells and compared to the recently demonstrated hybrid materials using bismuth instead of antimony. The hybrid compound is solution-processed onto the photoactive layer based on a classical blend, composed of PTB7-Th low bandgap polymer as donor mixed with PC70BM fullerene as acceptor material. By using a regular device structure and an aluminum cathode, the solar cells exhibited a power conversion efficiency of 8.42%, equivalent to the reference device using ZnO nanocrystals as interfacial layer, and strongly improved compared to bismuth-based hybrid material. The processing of extraction layers up to a thickness of 80 nm of such hybrid material reveals that the change from bismuth to antimony has strongly improved the charge extraction and transport properties of the hybrid materials. Interestingly, nanocomposites made of the hybrid material mixed with ZnO nanocrystals in a 1:1 ratio further improved the electronic properties of the extraction layers, leading to power conversion efficiency of 9.74%. This was addressed to a more closely packed morphology of the hybrid layer, leading to further improved electron extraction. It is important to note that these hybrid electron extraction layers, both pure and ZnO-doped, also greatly improved the stability of solar cells, both under dark storage in air and under lighting under inert atmosphere compared to solar cells treated with ZnO intermediate layers.