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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Masania, Kunal
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (34/34 displayed)
- 20243D Printing of Lead-Free Piezoelectric Ultrasound Transducers
- 2024Engineered living composite materialscitations
- 20233D Printing of Flow-Inspired Anisotropic Patterns with Liquid Crystalline Polymerscitations
- 2022Three-dimensional printing of mycelium hydrogels into living complex materialscitations
- 2022Light-Based Printing of Leachable Salt Molds for Facile Shaping of Complex Structurescitations
- 20213D Printed Scaffolds for Monolithic Aerogel Photocatalysts with Complex Geometriescitations
- 2021High-performance all-bio-based laminates derived from delignified woodcitations
- 2021Experimental and numerical investigation of ply size effects of steel foil reinforced compositescitations
- 2020Bio-Inspired Platelet-Reinforced Polymers with Enhanced Stiffness and Damping Behaviorcitations
- 2019Tunable wood by reversible interlocking and bioinspired mechanical gradientscitations
- 2019Fabrication of flax fibre-reinforced cellulose propionate thermoplastic compositescitations
- 2019Damping behaviour of bio-inspired natural fibre composites
- 2019Delignified wood–polymer interpenetrating composites exceeding the rule of mixturescitations
- 2019Tunable Wood by Reversible Interlocking and Bioinspired Mechanical Gradientscitations
- 2019Densified cellulose materials and delignified wood reinforced composites
- 2019Quantifying the role of mineral bridges on the fracture resistance of nacre-like composites
- 2018Predicting the adhesion strength of thermoplastic/glass interfaces from wetting measurementscitations
- 2018Interfacial interactions in bicomponent polymer fiberscitations
- 2018Three-dimensional printing of hierarchical liquid-crystal-polymer structurescitations
- 2018Local reinforcement of aerospace structures using co-curing RTM of metal foil hybrid compositescitations
- 2018The fracture of thermosetting epoxy polymers containing silica nanoparticlescitations
- 2017Damping of carbon fibre and flax fibre angle-ply composite laminatescitations
- 2017Wettability and interphase adhesion of molten thermoplastics on glass fibres
- 2017The fracture of thermosetting polymers containing silica nanoparticles
- 2017Mineral Nano-Interconnectivity Stiffens and Toughens Nacre-like Composite Materialscitations
- 2017Rheological modelling of thermoset composite processingcitations
- 2016Damping of carbon fibre and flax fibre reinforced angle ply polymers
- 2016Mechanical properties of tough plasma treated flax fibre thermoplastic composites
- 2016Effect of fibre volume content on the mechanical performance of natural fibre reinforced thermoplastic composites
- 2015Experimental study of the stress transfer in discontinuous composites on the basis of a unit cell model
- 2015Steel foil reinforced composites
- 2015A process modeling toolkit developed to address scale-up challenges of out-of-autoclave manufacturing
- 2011Toughening of epoxy using core-shell particlescitations
- 2008The fracture of glass-fibre-reinforced epoxy composites using nanoparticle-modified matricescitations
Places of action
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article
Delignified wood–polymer interpenetrating composites exceeding the rule of mixtures
Abstract
Wood is increasingly considered in sustainable structural materials development due to its hierarchical structure, including an oriented reinforcing cellulose phase combined with carbon capturing and renewability. Top-down manufacturing techniques can provide direct access to this hierarchical cellulose scaffold for use in new functional materials. For high-performance load-bearing wood-based materials, the volume content of the reinforcing phase needs to be increased to much higher fiber volume contents (FVCs). This has been achieved by structure-retaining delignification followed by densification. The obtained matrix-free materials possess high tensile stiffness due to preservation of hierarchical fiber alignment; however, they demonstrate low mechanical properties in bending and cannot be used in moist conditions due to their propensity for water absorption. In order to address these two challenges, an interpenetrating wood polymer phase composite is developed using a delignified wood scaffold as a continuous reinforcing phase and epoxy resin as the interconnected matrix phase. We utilize the continuous flow channels in delignified wood for vacuum-assisted matrix infiltration in a condition of open continuous porosity in the wood scaffold. Prior to matrix curing, the material is densified in order to increase the FVC, decrease porosity, and reduce density variations in the wood scaffold. Due to the compressibility of delignified cellulose fibers, interpenetrating phase composites (IPCs) with very high FVCs of up to 80% could be produced, leading to exceptionally high tensile stiffness and strength of up to 70 GPa and 600 MPa. The obtained stiffness values far exceed the upper limit of the rule of mixtures due to an enhanced stress transfer through mechanically interlocked fiber–fiber interfaces combined with the stiffness providing matrix phase that further aids stress transfer between neighboring wood cells via their pits. This new approach paves the way for an efficient production of high-performance ...