| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Lindsay, Robert
University of Manchester
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2023Sweet Corrosion Scale: Structure and Energetics of Siderite Facetscitations
- 2022Corrosion Inhibition in Acidic Environments: Key Interfacial Insights with Photoelectron Spectroscopycitations
- 2020An Exemplar Imidazoline Surfactant for Corrosion Inhibitor Studies:Synthesis, Characterization, and Physicochemical Propertiescitations
- 2019Corrosion protection through naturally occurring films: new insights from iron carbonatecitations
- 2017Structure of the SnO2(110)-(4 x 1) Surfacecitations
- 2017Determining the Chemical Composition of Corrosion Inhibitor/Metal Interfaces with XPS: Minimizing Post Immersion Oxidationcitations
- 2017Structure of the SnO2(110)-(4 × 1) surfacecitations
- 2017Structure of the SnO2 (110)- (4×1) Surfacecitations
- 2015Microscopic study of the corrosion behaviour of mild steel in ionic liquids for CO2 capture applicationscitations
- 2015In Situ Grazing Incidence X-ray Diffraction of Sweet Corrosion Scaling on Carbon Steel
- 2014Corrosion behaviour of mild steel in 1-alkyl-3-methylimidazolium tricyanomethanide ionic liquids for CO2 capture applications
- 2014Corrosion Inhibition Performance of 2-Mercaptobenzimidazole in Sweet Oilfield Conditions
- 2005Revisiting the surface structure of TiO2(110): A quantitative low-energy electron diffraction studycitations
- 2004ZnO(0001̄)-O surface structure:Hydrogen-free (1 × 1) terminationcitations
- 2004ZnO(0001̄)-O surface structurecitations
Places of action
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article
Corrosion protection through naturally occurring films: new insights from iron carbonate
Abstract
Despite intensive study over many years, the chemistry and physics<br/>of the atomic level mechanisms that govern corrosion are not fully understood. In particular, the occurrence and severity of highly localized metal degradation cannot currently be predicted and often cannot be rationalized in failure analysis. We report a first-principles model of the nature of protective iron carbonate films coupled with a detailed chemical and physical characterization of such a film in a carefully controlled environment. The fundamental building blocks of the protective film, siderite (FeCO3) crystallites, are found to be very sensitive to the growth environment. In iron-rich conditions, cylindrical crystallites form that are highly likely to be more susceptible to chemical attack and dissolution than the rhombohedral crystallites formed in iron-poor conditions. This suggests that local degradation of metal surfaces is influenced by structures that form during early growth and provides new avenues for the prevention, detection, and mitigation of carbon steel corrosion. <br/><br/>