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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Wang, Junke
University of Oxford
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 20233D Perovskite Passivation with a Benzotriazole-Based 2D Interlayer for High-Efficiency Solar Cellscitations
- 20233D Perovskite Passivation with a Benzotriazole-Based 2D Interlayer for High-Efficiency Solar Cells.
- 20233D perovskite passivation with a benzotriazole-based 2D interlayer for high-efficiency solar cellscitations
- 2022Monolithic All-Perovskite Tandem Solar Cells with Minimized Optical and Energetic Lossescitations
- 2021Ultralow dark current in near-infrared perovskite photodiodes by reducing charge injection and interfacial charge generationcitations
- 2021Use of Sodium Diethyldithiocarbamate to Enhance the Open-Circuit Voltage of CH3NH3PbI3 Perovskite Solar Cellscitations
- 2021Use of Sodium Diethyldithiocarbamate to Enhance the Open-Circuit Voltage of CH 3 NH 3 PbI 3 Perovskite Solar Cellscitations
- 202016.8% Monolithic all-perovskite triple-junction solar cells via a universal two-step solution processcitations
- 202016.8% Monolithic all-perovskite triple-junction solar cells via a universal two-step solution processcitations
- 2019Air-stable and oriented mixed lead halide perovskite (FA/MA) by the one-step deposition method using Zinc Iodide and an Alkylammonium additivecitations
- 2019Air-Stable and Oriented Mixed Lead Halide Perovskite (FA/MA) by the One-Step Deposition Method Using Zinc Iodide and an Alkylammonium Additivecitations
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article
Air-Stable and Oriented Mixed Lead Halide Perovskite (FA/MA) by the One-Step Deposition Method Using Zinc Iodide and an Alkylammonium Additive
Abstract
We present a one-step method to produce air-stable, large-grain mixed cationic lead perovskite films and powders under ambient conditions. The introduction of 2.5 % of Zn(II), confirmed by X-ray diffraction (XRD), results in stable thin films which show the same absorption and crystal structure after 2 weeks of storage under ambient conditions. Next to prolonged stability, the introduction of Zn(II) affects photophysical properties, reducing the bulk defect density, enhancing the photoluminescence (PL), and extending the charge carrier lifetime. Furthermore, 3-chloropropylamine hydrochloride is applied as the film-forming agent. The presence of this amine hydrochloride additive results in highly oriented and large crystal domains showing an ulterior improvement of PL intensity and lifetime. The material can also be prepared as black precursor powder by a solid–solid reaction under ambient conditions and can be pressed into a perovskite pellet. The prolonged stability and the easy fabrication in air makes this material suitable for large-scale, low-cost processing for optoelectronic applications.