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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Muscarella, Loreta A.
Utrecht University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2024Tuning the Optical and Structural Properties of Halide Perovskite by PbS Quantum Dot Additive Engineering for Enhanced Photovoltaic Performances
- 2024Tuning the Optical and Structural Properties of Halide Perovskite by PbS Quantum Dot Additive Engineering for Enhanced Photovoltaic Performances
- 2023Conduction band tuning by controlled alloying of Fe into Cs2AgBiBr6 double perovskite powderscitations
- 2021Shaping perovskites: in situ crystallization mechanism of rapid thermally annealed, prepatterned perovskite filmscitations
- 2021Shaping perovskites: in situ crystallization mechanism of rapid thermally annealed, prepatterned perovskite filmscitations
- 2021Accelerated Hot-Carrier Cooling in MAPbI3 Perovskite by Pressure-Induced Lattice Compressioncitations
- 2021Reduced Barrier for Ion Migration in Mixed-Halide Perovskitescitations
- 2020Thermodynamic stabilization of mixed-halide perovskites against phase segregationcitations
- 2019Air-stable and oriented mixed lead halide perovskite (FA/MA) by the one-step deposition method using Zinc Iodide and an Alkylammonium additivecitations
- 2019Air-Stable and Oriented Mixed Lead Halide Perovskite (FA/MA) by the One-Step Deposition Method Using Zinc Iodide and an Alkylammonium Additivecitations
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article
Air-Stable and Oriented Mixed Lead Halide Perovskite (FA/MA) by the One-Step Deposition Method Using Zinc Iodide and an Alkylammonium Additive
Abstract
We present a one-step method to produce air-stable, large-grain mixed cationic lead perovskite films and powders under ambient conditions. The introduction of 2.5 % of Zn(II), confirmed by X-ray diffraction (XRD), results in stable thin films which show the same absorption and crystal structure after 2 weeks of storage under ambient conditions. Next to prolonged stability, the introduction of Zn(II) affects photophysical properties, reducing the bulk defect density, enhancing the photoluminescence (PL), and extending the charge carrier lifetime. Furthermore, 3-chloropropylamine hydrochloride is applied as the film-forming agent. The presence of this amine hydrochloride additive results in highly oriented and large crystal domains showing an ulterior improvement of PL intensity and lifetime. The material can also be prepared as black precursor powder by a solid–solid reaction under ambient conditions and can be pressed into a perovskite pellet. The prolonged stability and the easy fabrication in air makes this material suitable for large-scale, low-cost processing for optoelectronic applications.