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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Correia, Daniela Maria Silva
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (22/22 displayed)
- 2023Humidity sensors based on magnetic ionic liquids blended in poly(vinylidene fluoride-co-hexafluoropropylene)citations
- 2023Multifunctional magnetoelectric sensing and bending actuator response of polymer-based hybrid materials with magnetic ionic liquidscitations
- 2023Solid polymer electrolytes based on a high dielectric polymer and ionic liquids for lithium batteriescitations
- 2023High performance ternary solid polymer electrolytes based on high dielectric poly(vinylidene fluoride) copolymers for solid state lithium-ion batteriescitations
- 2022Poly(lactic-co-glycolide) based biodegradable electrically and magnetically active microenvironments for tissue regeneration applicationscitations
- 2022Sustainable lithium-ion battery separators based on poly(3-Hydroxybutyrate-Co-Hydroxyvalerate) pristine and composite electrospun membranescitations
- 2022Poly(vinylidene fluoride-co-hexafluoropropylene) based tri-composites with zeolite and ionic liquid for electromechanical actuator and lithium-ion battery applicationscitations
- 2022Structural organization of ionic liquids embedded in fluorinated polymerscitations
- 2022Lithium-Ion battery solid electrolytes based on poly(vinylidene fluoride)-metal thiocyanate ionic liquid blendscitations
- 2022Ionic liquid-based electroactive materials: a novel approach for cardiac tissue engineering strategiescitations
- 2021Photocurable temperature activated humidity hybrid sensing materials for multifunctional coatingscitations
- 2021Enhanced ionic conductivity in poly(vinylidene fluoride) electrospun separator membranes blended with different ionic liquids for lithium ion batteriescitations
- 2021Thermal degradation behavior of ionic liquid/ fluorinated polymer composites: Effect of polymer type and ionic liquid anion and cationcitations
- 2020Polymer-based actuators: back to the futurecitations
- 2020Development of poly(l-Lactic Acid)-based bending actuatorscitations
- 2020Ionic liquid-polymer composites: a new platform for multifunctional applicationscitations
- 2020Lithium-ion battery separator membranes based on poly(L-lactic acid) biopolymercitations
- 2020Cellulose nanocrystal and water-soluble cellulose derivative based electromechanical bending actuatorscitations
- 2019Ionic-liquid-based printable materials for thermochromic and thermoresistive applicationscitations
- 2018Ionic and conformational mobility in poly(vinylidene fluoride)/ionic liquid blends: dielectric and electrical conductivity behaviorcitations
- 2018Low-field giant magneto-ionic response in polymer-based nanocompositescitations
- 2016Poly(vinylidene fluoride-hexafluoropropylene)/bayerite composites membranes for efficient arsenic water removalcitations
Places of action
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article
Ionic-liquid-based printable materials for thermochromic and thermoresistive applications
Abstract
Smart materials exhibiting thermochromic and themoresistive properties based on the electroactive polymer poly(vinylidene fluoride) (PVDF) and the ionic liquid (IL) bis(1-butyl-3-methylimidazolium) tetrachloronickelate ([Bmim](2)[NiCl4]) have been developed with different contents of [Bmim](2)[NiCl4] (10, 20, and 40 wt %) within the polymer matrix. The morphology of the composites is studied, and the thermochromic and thermoresistive properties are evaluated. Independently of the IL content, the PVDF/[Bmim](2)[NiCl4] composites present a porous morphology and thermochromic response, revealed by the color change of the composites from transparent to dark blue, attributed to the tetrahedral complex NiCl42- formed after a dehydration process. Further, the electrical conductivity increases with increasing IL content and decreases with increasing temperature. It is also shown that the incorporation of the IL into the PVDF matrix leads to an increase in the electroactive beta phase and a decrease in the degree of crystallinity and thermal stability with increasing [Bmim](2)[NiCl4] content. The printability and applicability of the developed materials as sensors are also demonstrated. ; The authors acknowledge the FCT-Fundacao para a Ciencia e Tecnologia-for financial support under the framework of the Strategic Funding UID/FIS/04650/2013, the Associated Laboratory Research Unit for Green Chemistry, Technologies and Clean Processes, LAQV (financed by national funds from FCT/MEC, UID/QUI/50006/2013, and ERDF under the PT2020, POCI-01-0145-FEDER-007265), and project PTDC/EEI-SII/5582/2014 by FEDER funds through the COMPETE 2020-Programa Operational Competitividade e Internacionalizacao (POCI) with the reference project POCI-01-0145-FEDER-006941. Funds provided by FCT in the framework of EuroNanoMed 2016 call, Project LungChek ENMed/0049/2016, are also gratefully acknowledged. D.M.C., N.P., and J.M.S.S.E. also acknowledge the grant/contract SFRH/BPD/121526/2016, SFRH/BD/131729/2017, and IF/00355/2012, respectively. The ...