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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Obot, Ime B.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2022Corrosion Inhibition of Rumex vesicarius Mediated Chitosan-AgNPs Composite for C1018 CS in CO2-Saturated 3.5% NaCl Medium under Static and Hydrodynamic Conditionscitations
- 2022Elucidation of corrosion inhibition property of compounds isolated from Butanolic Date Palm Leaves extract for low carbon steel in 15% HCl solutioncitations
- 2021Date palm leaves extract as a green and sustainable corrosion inhibitor for low carbon steel in 15 wt.% HCl solutioncitations
- 2021Effect of intensifier additives on the performance of butanolic extract of date palm leaves against the corrosion of api 5l x60 carbon steel in 15 wt.% hcl solutioncitations
- 2020Preparation of silver/chitosan nanofluids using selected plant extractscitations
- 2020Exploration of natural polymers for use as green corrosion inhibitors for AZ31 magnesium alloy in saline environmentcitations
- 2020Corrosion inhibition effect of a benzimidazole derivative on heat exchanger tubing materials during acid cleaning of multistage flash desalination plantscitations
- 2019Studies of the anticorrosion property of a newly synthesized Green isoxazolidine for API 5L X60 steel in acid environmentcitations
- 2018Comparative studies on the corrosion inhibition efficacy of ethanolic extracts of date palm leaves and seeds on carbon steel corrosion in 15% HCl solutioncitations
- 2018Exploration of Dextran for Application as Corrosion Inhibitor for Steel in Strong Acid Environmentcitations
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article
Exploration of Dextran for Application as Corrosion Inhibitor for Steel in Strong Acid Environment
Abstract
<p>The possibility of utilizing dextran as a green corrosion inhibitor for steel in strong acid environment was explore using weight loss, electrochemical (electrochemical impedance spectroscopy (EIS), electrochemical frequency modulation (EFM), potentiodynamic polarization (PDP), and linear polarization (LPR)) supported with surface analysis via scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDAX), atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS) techniques. The effect of molecular weight, temperature, and modification on the inhibition efficiency of dextran was also studied. Results from all the applied techniques reveal that dextran exhibit moderate anticorrosion property toward St37-2 steel dissolution in 15% H<sub>2</sub>SO<sub>4</sub> solution. Dextran with molecular weight of 100 000-200 000 g/mol (Dex 1) exhibited the highest inhibition efficiency of 51.38% at 25 °C. Based on PDP results, dextran behaved as a mixed type corrosion inhibitor. Inhibition efficiency of dextran varies inversely with molecular weight but directly with temperature. Two modification approaches, namely incorporation of silver nanoparticles (AgNPs) into dextran matrices and combination with 1 mM KI were adopted to enhance the inhibition efficiency of dextran and the approaches proved effective. The protective capability of Dex 1 has been upgraded from 51.38% to 86.82% by infusion of AgNPs and to 94.21% by combination with KI at 25 °C. Results from the study on the effect of temperature reveals that Dex 1 + KI mixture could synergistically offer 99.4% protection to St37-2 steel in 15% H<sub>2</sub>SO<sub>4</sub> environment at 60 °C. Surface analysis results confirm the presence of additives molecules on the studied metal surface. XPS results disclose that AgNPs are in oxide form while iodide ions are in the form of triiodide and pentaiodide ions on the metal surface. Modified dextran is a promising candidate for application as corrosion inhibitor in acid induced corrosive environment.</p>