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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Von Hauff, Elizabeth
Fraunhofer Society
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (27/27 displayed)
- 2024Volumetric 3D-Printed Piezoelectric Polymer Filmscitations
- 2021Correlating Ultrafast Dynamics, Liquid Crystalline Phases, and Ambipolar Transport in Fluorinated Benzothiadiazole Dyescitations
- 2021Correlating Ultrafast Dynamics, Liquid Crystalline Phases, and Ambipolar Transport in Fluorinated Benzothiadiazole Dyescitations
- 2019Air-stable and oriented mixed lead halide perovskite (FA/MA) by the one-step deposition method using Zinc Iodide and an Alkylammonium additivecitations
- 2019Relating Chain Conformation to the Density of States and Charge Transport in Conjugated Polymers:The Role of the β -phase in Poly(9,9-dioctylfluorene)citations
- 2019Air-Stable and Oriented Mixed Lead Halide Perovskite (FA/MA) by the One-Step Deposition Method Using Zinc Iodide and an Alkylammonium Additivecitations
- 2019Relating Chain Conformation to the Density of States and Charge Transport in Conjugated Polymers: The Role of the β -phase in Poly(9,9-dioctylfluorene)citations
- 2019Relating Chain Conformation to the Density of States and Charge Transport in Conjugated Polymerscitations
- 2018Extraordinary Interfacial Stitching between Single All-Inorganic Perovskite Nanocrystalscitations
- 2018Extraordinary Interfacial Stitching between Single All-Inorganic Perovskite Nanocrystalscitations
- 2016High-Permittivity Conjugated Polyelectrolyte Interlayers for High-Performance Bulk Heterojunction Organic Solar Cellscitations
- 2016High-Permittivity Conjugated Polyelectrolyte Interlayers for High-Performance Bulk Heterojunction Organic Solar Cellscitations
- 2015Imaging of morphological changes and phase segregation in doped polymeric semiconductorscitations
- 2015Imaging of morphological changes and phase segregation in doped polymeric semiconductorscitations
- 2013Silica Nanoparticles for Enhanced Carrier Transport in Polymer-Based Short Channel Transistorscitations
- 2013Silica Nanoparticles for Enhanced Carrier Transport in Polymer-Based Short Channel Transistorscitations
- 2013Thiophene-based copolymers synthesized by electropolymerization for application as hole transport layer in organic solar cellscitations
- 2013Interpreting the density of states extracted from organic solar cells using transient photocurrent measurementscitations
- 2012The Effect of Ageing on Exciton Dynamics, Charge Separation, and Recombination in P3HT/PCBM Photovoltaic Blendscitations
- 2012The Effect of Ageing on Exciton Dynamics, Charge Separation, and Recombination in P3HT/PCBM Photovoltaic Blendscitations
- 2012Influence of different copolymer sequences in low band gap polymers on their performance in organic solar cellscitations
- 2012ITO-free inverted polymer/fullerene solar cells: Interface effects and comparison of different semi-transparent front contactscitations
- 2012Influence of molecular weight on the short-channel effect in polymer-based field-effect transistorscitations
- 2011The Role of Molecular Structure and Conformation in Polymer Electronicscitations
- 2009Electrochemical Synthesis of Polypyrrole Layers Doped with Glutamic Ionscitations
- 2008Binding and release of glutamate from overoxidized polypyrrole via an applied potential for application as a molecular switchcitations
- 2005Diphenylmethanofullerenes: New and efficient acceptors in bulk-heterojunction solar cellscitations
Places of action
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article
Extraordinary Interfacial Stitching between Single All-Inorganic Perovskite Nanocrystals
Abstract
<p>All-inorganic cesium lead halide perovskite nanocrystals are extensively studied because of their outstanding optoelectronic properties. Being of a cubic shape and typically featuring a narrow size distribution, CsPbX<sub>3</sub> (X = Cl, Br, and I) nanocrystals are the ideal starting material for the development of homogeneous thin films as required for photovoltaic and optoelectronic applications. Recent experiments reveal spontaneous merging of drop-casted CsPbBr<sub>3</sub> nanocrystals, which is promoted by humidity and mild-temperature treatments and arrested by electron beam irradiation. Here, we make use of atom-resolved annular dark-field imaging microscopy and valence electron energy loss spectroscopy in a state-of-the-art low-voltage monochromatic scanning transmission electron microscope to investigate the aggregation between individual nanocrystals at the atomic level. We show that the merging process preserves the elemental composition and electronic structure of CsPbBr<sub>3</sub> and takes place between nanocrystals of different sizes and orientations. In particular, we reveal seamless stitching for aligned nanocrystals, similar to that reported in the past for graphene flakes. Because the crystallographic alignment occurs naturally in drop-casted layers of CsPbX<sub>3</sub> nanocrystals, our findings constitute the essential first step toward the development of large-area nanosheets with band gap energies predesigned by the nanocrystal choice - the gateway to large-scale photovoltaic applications of inorganic perovskites.</p>