| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Daasbjerg, Kim
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2023Interfacial Engineering of PVDF-TrFE toward Higher Piezoelectric, Ferroelectric, and Dielectric Performance for Sensing and Energy Harvesting Applicationscitations
- 2023Interfacial Engineering of PVDF-TrFE toward Higher Piezoelectric, Ferroelectric, and Dielectric Performance for Sensing and Energy Harvesting Applicationscitations
- 2023Steering carbon dioxide reduction toward C–C coupling using copper electrodes modified with porous molecular filmscitations
- 2023Interfacial Engineering of PVDF‐TrFE toward Higher Piezoelectric, Ferroelectric, and Dielectric Performance for Sensing and Energy Harvesting Applicationscitations
- 2022Can the CO 2 Reduction Reaction Be Improved on Cu:Selectivity and Intrinsic Activity of Functionalized Cu Surfacescitations
- 2022Can the CO2Reduction Reaction Be Improved on Cucitations
- 2020Restructuring Metal–Organic Frameworks to Nanoscale Bismuth Electrocatalysts for Highly Active and Selective CO 2 Reduction to Formatecitations
- 2020Achieving Near-Unity CO Selectivity for CO 2 Electroreduction on an Iron-Decorated Carbon Materialcitations
- 2020Restructuring Metal–Organic Frameworks to Nanoscale Bismuth Electrocatalysts for Highly Active and Selective CO<sub>2</sub> Reduction to Formatecitations
- 2020Stimuli-responsive degrafting of polymer brushes via addressable catecholato-metal attachmentscitations
- 2020Stimuli-responsive degrafting of polymer brushes via addressable catecholato-metal attachmentscitations
- 2020Non-enzymatic Electroanalytical Sensing of Glucose Based on Nano Nickel-Coordination Polymers-Modified Glassy Carbon Electrodecitations
- 2020Restructuring Metal–Organic Frameworks to Nanoscale Bismuth Electrocatalysts for Highly Active and Selective $CO_{2}$ Reduction to Formatecitations
- 2020Facile Access to Disulfide/Thiol Containing Poly(glycidyl methacrylate) Brushes as Potential Rubber Adhesive Layerscitations
- 2020Facile Access to Disulfide/Thiol Containing Poly(glycidyl methacrylate) Brushes as Potential Rubber Adhesive Layerscitations
- 2018Facile Synthesis of Iron- and Nitrogen-Doped Porous Carbon for Selective CO 2 Electroreductioncitations
- 2018Efficient bonding of ethylene-propylene-diene M-class rubber to stainless steel using polymer brushes as a nanoscale adhesivecitations
- 2017Efficient Graphene Production by Combined Bipolar Electrochemical Intercalation and High-Shear Exfoliationcitations
- 2016Hydrophilic Polymer Brush Layers on Stainless Steel Using Multilayered ATRP Initiator Layercitations
- 2016Electrochemical procedure for constructing poly(phenylene sulfide) brushes on glassy carbon and stainless steelcitations
- 2014Durability of PEEK adhesive to stainless steel modified with aryldiazonium saltscitations
Places of action
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article
Hydrophilic Polymer Brush Layers on Stainless Steel Using Multilayered ATRP Initiator Layer
Abstract
Thin polymer coatings (in tens of nanometers to a micron thick) are desired on industrial surfaces such as stainless steel. In this thickness range coatings are difficult to produce using conventional methods. In this context, surface-initiated controlled polymerization method can offer a promising tool to produce thin polymer coatings via bottom-up approach. Furthermore, the industrial surfaces are chemically heterogeneous and exhibit surface features in the form of grain boundaries and grain surfaces. Therefore, the thin coatings must be equally effective on both the grain surfaces and the grain boundary regions. This study illustrates a novel "periodic rejuvenation of surface initiation" process using surface-initiated ATRP technique to amplify the graft density of poly(oligoethylene glycol)methacrylate (POEGMA) brush layers on stainless steel 316L surface. The optimized conditions demonstrate a controlled, macroscopically homogeneous, and stable POEGMA brush layer covering both the grain surface and the grain boundary region. Various relevant parameters - surface cleaning methods, controllability of thickness, graft density, homogeneity and stability - were studied using techniques such as ellipsometer, X-ray photoelectron spectroscopy, scanning electron microscopy-energy-dispersive X-ray, surface zeta potential, and infrared reflection-adsorption spectroscopy.