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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Jaffrezic-Renault, Nicole
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (47/47 displayed)
- 2024Design of New Partially Bio-Based Polyguanamines for the Reversible Adsorption of Phenolic Molecules from Olive Mill Wastes
- 2023Experimental and theoretical study of polysaccharides extracted from prickly pear nopales Pulp (PPUN) of Opuntia ficus-indica as corrosion inhibitorscitations
- 2023Electrochemical Sensors Based on Metal-Organic Framework and Conductive Polymer HKUST-1@PANI for High-Performance Detection of Lead Ionscitations
- 2023Label free electrochemical sensors for Pb(II) detection based on hemicellulose extracted from Opuntia Ficus Indica cactus ; Capteurs électrochimiques sans marquage pour la détection du Pb(II) à base d'hémicellulose extraite du cactus Opuntia Ficus Indicacitations
- 2023A novel conductometric sensor for acetone detection prepared through electro-polymerization of pyrrole-tailed ionic liquid
- 2023An Electrochemical Sensor for Sulfadiazine Determination Based on a Copper Nanoparticles/Molecularly Imprinted Overoxidized Polypyrrole Compositecitations
- 2022Highly stable and ultra-sensitive amperometric aptasensor based on pectin stabilized gold nanoparticles on graphene oxide modified GCE for the detection of aflatoxin M1citations
- 2022A Molecularly Imprinted Polypyrrole/GO@Fe3O4 Nanocomposite Modified Impedimetric Sensor for the Routine Monitoring of Lysozymecitations
- 2022A Molecularly Imprinted Polypyrrole/GO@Fe3O4 Nanocomposite Modified Impedimetric Sensor for the Routine Monitoring of Lysozymecitations
- 2022Review—Recent Progress in Graphene Based Modified Electrodes for Electrochemical Detection of Dopaminecitations
- 2022Zero-Valent Iron Nanoparticles Supported on Biomass-Derived Porous Carbon for Simultaneous Detection of Cd2+ and Pb2+ ; Nanoparticules de fer valence zéro fixées sur du carbone poreux issu de biomasse pour la détection simultanée de Cd2+ et de Pb2+.citations
- 2021Sensitive Electrochemical Detection of Bioactive Molecules (Hydrogen Peroxide, Glucose, Dopamine) with Perovskites-Based Sensorscitations
- 2021Detection of Gadolinium with an Impedimetric Platform Based on Gold Electrodes Functionalized by 2-Methylpyridine-Substituted Cyclamcitations
- 2021Application of new aptasensor modified with nanocomposite for selective estradiol valerate determination in pharmaceutical and real biological samplescitations
- 2020Voltammetric Sensor Based on Molecularly Imprinted Chitosan-Carbon Nanotubes Decorated with Gold Nanoparticles Nanocomposite Deposited on Boron-Doped Diamond Electrodes for Catechol Detectioncitations
- 2020Highly Sensitive Voltammetric Catechol Biosensor Based on Electroaddressing of Laccase Encapsulated in Modified Chitosancitations
- 2020Experimental Study and Mathematical Modeling of a Glyphosate Impedimetric Microsensor Based on Molecularly Imprinted Chitosan Filmcitations
- 2020Experimental Study and Mathematical Modeling of a Glyphosate Impedimetric Microsensor Based on Molecularly Imprinted Chitosan Filmcitations
- 2018Electrochemical properties of nitrogen-doped graphene for environmental sensors
- 2017Gold Nanoparticle/Polymer/Enzyme Nanocomposite for the Development of Adenosine Triphosphate Biosensorcitations
- 2016Development of a novel sensitive molecularly imprinted polymer sensor based on electropolymerization of a microporous-metal-organic framework for tetracycline detection in honeycitations
- 2016Effect of pH on the detection of metal ions using a ISFET sensor modified with a polysiloxane film substituted by naphtyl-cyclamcitations
- 2016A new sensitive and selective sensor for heavy metal ions based on tannin extracted from the skin of Punica granatum Lcitations
- 2016Robust Electrografting on Self-Organized 3D Graphene Electrodescitations
- 2016Structure, electrochemical properties and functionalization of amorphous CN films deposited by femtosecond pulsed laser ablationcitations
- 2015Thermolysin entrapped in a gold nanoparticles/polymer composite for direct and sensitive conductometric biosensing of ochratoxin A in olive oilcitations
- 20151,3,5-Trinitrotoluene detection by a molecularly imprinted polymer sensor based on electropolymerization of a microporous-metal-organic frameworkcitations
- 2015Aflatoxin B1 detection using a highly-sensitive molecularly-imprinted electrochemical sensor based on an electropolymerized metal organic frameworkcitations
- 2015Structural and electrochemical properties of amorphous carbon nitride films deposited by femtosecond pulsed laser ablation
- 2015Molecularly imprinted polymer-based electrochemical sensor for the sensitive detection of glyphosate herbicidecitations
- 2015Development of a capacitive chemical sensor based on Co(II)-phthalocyanine acrylate-polymer/HfO2/SiO2/Si for detection of perchloratecitations
- 2015Nanosized zeolites as a perspective material for conductometric biosensors creationcitations
- 2013Development of a flexible microfluidic system based on a simple and reproducible sealing process between polymers and poly(dimethylsiloxane)citations
- 2013Comparative Study of Responses of Two Enzymatic Biosensors Based on Lipase from Candida rugosa and Porcine Pancreas for Detection of Diclofop-Methylcitations
- 2012Diazonium modified gold microelectrodes onto polyimide substrates for impedimetric cytokine detection with an integrated Ag/AgCl reference electrodecitations
- 2011Electrochemical impedance detection of Hg(2+), Ni(2+) and Eu(3+) ions by a new azo-calix[4]arene membranecitations
- 2011Electrochemical impedance detection of Hg(2+), Ni(2+) and Eu(3+) ions by a new azo-calix(4)arene membranecitations
- 2010Molecularly imprinted polymers (MIP) based electrochemical sensor for detection of urea and creatininecitations
- 2010Effect of electrical conditions on an impedimetric immunosensor based on a modified conducting polypyrrolecitations
- 2009Escherichia Coli functionalized magnetic nanobeads as an ultrasensitive biosensor for heavy metalscitations
- 2006Detection of heavy metals by an optical fiber sensor with a sensitive cladding including a new chromogenic calix[4]arene molecule
- 2006Tribological response of sterilized and un-sterilized orthodontic wires
- 2006Effect of surface treatment and functionalization on the ITO properties for OLEDs
- 2006Sensitivity and specificity improvement of an ion sensitive field effect transistors-based biosensor for potato glycoalkaloids detection
- 2005Study of a new evanescent wave optical fibre sensor for methane detection based on cryptophane moleculescitations
- 2005EIS field effect structures functionalized by p-tert-butylcalix[6]arene for Ni2+ detectioncitations
- 2004Electrodeposited biotinylated polypyrrole as an immobilization method for impedimetric immunosensorscitations
Places of action
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article
Robust Electrografting on Self-Organized 3D Graphene Electrodes
Abstract
International audience ; Improving graphene-based electrode fabrication processes and developing robust methods for its functionalization are two key research routes to develop new high-performance electrodes for electrochemical applications. Here, a self-organized three-dimensional (3D) graphene electrode processed by pulsed laser deposition with thermal annealing is reported. This substrate shows great performance in electron transfer kinetics regarding ferrocene redox probes in solution. A robust electrografting strategy for covalently attaching a redox probe onto these graphene electrodes is also reported. The modification protocol consists of a combination of diazonium salt electrografting and click chemistry. An alkyne-terminated phenyl ring is first electrografted onto the self-organized 3D graphene electrode by in situ electrochemical reduction of 4-ethynylphenyl diazonium. Then the ethynylphenyl-modified surface efficiently reacts with the redox probe bearing a terminal azide moiety (2-azidoethyl ferrocene) by means of Cu-I-catalyzed alkyne-azide cycloaddition. Our modification strategy applied to 3D graphene electrodes was analyzed by means of atomic force microscopy, scanning electron microscopy, Raman spectroscopy, cyclic voltammetry, and X-ray photoelectron spectroscopy (XPS). For XPS chemical surface analysis, special attention was paid to the distribution and chemical state of iron and nitrogen in order to highlight the functionalization of the graphene-based substrate by electrochemically grafting a ferrocene derivative. Dense grafting was observed, offering 4.9 X 10(-10) mol cm(-2) surface coverage and showing a stable signal over 22 days. The electrografting was performed in the form of multilayers, which offers higher ferrocene loading than a dense monolayer on a flat surface. This work opens highly promising perspectives for the development of self-organized 3D graphene electrodes with various sensing functionalities.