| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Vivo, Paola
Tampere University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (46/46 displayed)
- 2024Lattice Engineering via Transition Metal Ions for Boosting Photoluminescence Quantum Yields of Lead-Free Layered Double Perovskite Nanocrystalscitations
- 2024Lattice Engineering via Transition Metal Ions for Boosting Photoluminescence Quantum Yields of Lead-Free Layered Double Perovskite Nanocrystalscitations
- 2024Lattice Engineering via Transition Metal Ions for Boosting Photoluminescence Quantum Yields of Lead-Free Layered Double Perovskite Nanocrystalscitations
- 2024Probing compositional engineering effects on lead-free perovskite-inspired nanocrystal thin films using correlative nonlinear optical microscopycitations
- 2024Surface-Engineered Cesium Lead Bromide Perovskite Nanocrystals for Enabling Photoreduction Activitycitations
- 2024Assessing the Environmental Impact of Pnictogen-based Perovskite-Inspired Materials for Indoor Photovoltaicscitations
- 2024Simplifying perovskite solar cell fabrication for materials testing : how to use unetched substrates with the aid of a three-dimensionally printed cell holder
- 2024Perovskite‐Inspired Cs₂AgBi₂I₉: A Promising Photovoltaic Absorber for Diverse Indoor Environmentscitations
- 2024Halide Perovskites for Photoelectrochemical Water Splitting and CO2 Reductioncitations
- 2024Synergistic metal halide perovskite@metal-organic framework hybrids for photocatalytic CO2 reductioncitations
- 2024Halide Engineering in Mixed Halide Perovskite-Inspired Cu2AgBiI6 for Solar Cells with Enhanced Performancecitations
- 2024Probing compositional engineering effects on lead-free perovskiteinspired nanocrystal thin films using correlative nonlinear optical microscopycitations
- 2023Introduction
- 2023Wide‐Bandgap Perovskite‐Inspired Materials: Defect‐Driven Challenges for High‐Performance Optoelectronicscitations
- 2023Water-resistant perovskite-inspired copper/silver pnictohalide nanocrystals for photoelectrochemical water splittingcitations
- 2023Water-resistant perovskite-inspired copper/silver pnictohalide nanocrystals for photoelectrochemical water splittingcitations
- 2023Wide-bandgap perovskite-inspired materials: defect-driven challenges for high-performance optoelectronicscitations
- 2023Antimony-Bismuth Alloying : The Key to a Major Boost in the Efficiency of Lead-Free Perovskite-Inspired Photovoltaicscitations
- 2023Triple A-Site Cation Mixing in 2D Perovskite-Inspired Antimony Halide Absorbers for Efficient Indoor Photovoltaicscitations
- 2023Triple A-Site Cation Mixing in 2D Perovskite-Inspired Antimony Halide Absorbers for Efficient Indoor Photovoltaicscitations
- 2023Lead-free perovskite-inspired semiconductors for indoor light-harvesting - the present and the futurecitations
- 2023Lead-free perovskite-inspired semiconductors for indoor light-harvesting - the present and the futurecitations
- 2023Screening Mixed-Metal Sn2M(III)Ch2X3 Chalcohalides for Photovoltaic Applicationscitations
- 2023Antimony‐Bismuth Alloying: The Key to a Major Boost in the Efficiency of Lead‐Free Perovskite‐Inspired Photovoltaicscitations
- 2023Antimony-Bismuth Alloyingcitations
- 2022Flexible Organic Photovoltaics with Star-Shaped Nonfullerene Acceptors End Capped with Indene Malononitrile and Barbiturate Derivativescitations
- 2021Tuning halide perovskite energy levelscitations
- 2021Tuning halide perovskite energy levelscitations
- 2021Fluorination of pyrene-based organic semiconductors enhances the performance of light emitting diodes and halide perovskite solar cellscitations
- 2021There is plenty of room at the topcitations
- 2020Monitoring Charge Carrier Diffusion across a Perovskite Film with Transient Absorption Spectroscopycitations
- 2020Femto- to Microsecond Dynamics of Excited Electrons in a Quadruple Cation Perovskitecitations
- 2020Femto- to Microsecond Dynamics of Excited Electrons in a Quadruple Cation Perovskitecitations
- 2020Tuning halide perovskite energy levelscitations
- 2020Fluorination of pyrene-based organic semiconductors enhances the performance of light emitting diodes and halide perovskite solar cellscitations
- 2020Fluorination of pyrene-based organic semiconductors enhances the performance of light emitting diodes and halide perovskite solar cellscitations
- 2020Investigation of well-defined pinholes in TiO 2 electron selective layers used in planar heterojunction perovskite solar cellscitations
- 2020Investigation of well-defined pinholes in TiO2 electron selective layers used in planar heterojunction perovskite solar cellscitations
- 2019Nano-structured TiO2 grown by low-temperature reactive sputtering for planar perovskite solar cellscitations
- 2019Refractive index change dominates the transient absorption response of metal halide perovskite thin films in the near infraredcitations
- 2019Highly Compact TiO<sub>2</sub> Films by Spray Pyrolysis and Application in Perovskite Solar Cellscitations
- 2019Eco-friendly and low-cost phenothiazine-based hole-transporting material for high performance perovskite solar cells
- 2017Impact of Film Thickness of Ultrathin Dip-Coated Compact TiO2 Layers on the Performance of Mesoscopic Perovskite Solar Cellscitations
- 2017Crystallisation-enhanced bulk hole mobility in phenothiazine-based organic semiconductorscitations
- 2017Tailored Fabrication of Transferable and Hollow Weblike Titanium Dioxide Structurescitations
- 2017Tailored Fabrication of Transferable and Hollow Weblike Titanium Dioxide Structurescitations
Places of action
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article
Surface-Engineered Cesium Lead Bromide Perovskite Nanocrystals for Enabling Photoreduction Activity
Abstract
<p>In recent years, colloidal lead halide perovskite (LHP) nanocrystals (NCs) have exhibited such intriguing light absorption properties to be contemplated as promising candidates for photocatalytic conversions. However, for effective photocatalysis, the light harvesting system needs to be stable under the reaction conditions propaedeutic to a specific transformation. Unlike photoinduced oxidative reaction pathways, photoreductions with LHP NCs are challenging due to their scarce compatibility with common hole scavengers like amines and alcohols. In this contribution, it is investigated the potential of CsPbBr<sub>3</sub> NCs protected by a suitably engineered bidentate ligand for the photoreduction of quinone species. Using an in situ approach for the construction of the passivating agent and a halide excess environment, quantum-confined nanocubes (average edge length = 6.0 ± 0.8 nm) are obtained with a low ligand density (1.73 ligand/nm<sup>2</sup>) at the NC surface. The bifunctional adhesion of the engineered ligand boosts the colloidal stability of the corresponding NCs, preserving their optical properties also in the presence of an amine excess. Despite their relatively short exciton lifetime (τ<sub>AV</sub> = 3.7 ± 0.2 ns), these NCs show an efficient fluorescence quenching in the presence of the selected electron accepting quinones (1,4-naphthoquinone, 9,10-phenanthrenequinone, and 9,10-anthraquinone). All of these aspects demonstrate the suitability of the NCs for an efficient photoreduction of 1,4-naphthoquinone to 1,4-dihydroxynaphthalene in the presence of triethylamine as a hole scavenger. This chemical transformation is impracticable with conventionally passivated LHP NCs, thereby highlighting the potential of the surface functionalization in this class of nanomaterials for exploring new photoinduced reactivities.</p>