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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Gonzalez-Garcia, Yaiza
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (27/27 displayed)
- 2024Review of the state of art of Li-based inhibitors and coating technology for the corrosion protection of aluminium alloyscitations
- 2024Albumin Protein Impact on Early-Stage In Vitro Biodegradation of Magnesium Alloy (WE43)citations
- 2024Spatiotemporally resolved corrosion protection of AA2024-T3 by a lithium-based conversion layercitations
- 2024Effects of grain boundary chemistry and precipitate structure on intergranular corrosion in Al-Mg-Si alloys doped with Cu and Zncitations
- 2023Corrosion and passive film characteristics of 3D-printed NiTi shape memory alloys in artificial salivacitations
- 2023Local scanning electrochemical microscopy analysis of a lithium-based conversion layer on AA2024-T3 at progressive stages of formationcitations
- 2023Passive film formation and corrosion resistance of laser-powder bed fusion fabricated NiTi shape memory alloyscitations
- 2023Challenges and Strategies for Optimizing Corrosion and Biodegradation Stability of Biomedical Micro‐ and Nanoswimmers: A Reviewcitations
- 2022Evaluation of the formation and protectiveness of a lithium-based conversion layer using electrochemical noisecitations
- 2022Localised aqueous corrosion of electroless nickel immersion gold-coated coppercitations
- 2022Passive Film Properties of Martensitic Steels in Alkaline Environment: Influence of the Prior Austenite Grain Sizecitations
- 2022Corrosion and Microstructural Investigation on Additively Manufactured 316L Stainless Steel: Experimental and Statistical Approachcitations
- 2021Editors' Choice - Dealloying-Driven Cerium Precipitation on Intermetallic Particles in Aerospace Aluminium Alloyscitations
- 2020Effect of surface roughness and chemistry on the adhesion and durability of a steel-epoxy adhesive interfacecitations
- 2019Self-healing epoxy nanocomposite coatings based on dual-encapsulation of nano-carbon hollow spheres with film-forming resin and curing agentcitations
- 2018Properties and performance of spin-on-glass coatings for the corrosion protection of stainless steels in chloride media
- 2018Additively manufactured biodegradable porous ironcitations
- 2017Use of local electrochemical methods (SECM, EC-STM) and AFM to differentiate microstructural effects (EBSD) on very pure coppercitations
- 2017Electrochemical evaluation of corrosion inhibiting layers formed in a defect from lithium-leaching organic coatingscitations
- 2017Corrosion Resistance of AISI 316L Coated with an Air-Cured Hydrogen Silsesquioxane Based Spin-On-Glass Enamel in Chloride Environmentcitations
- 2016Micro-biologically induced steel corrosion and corrosion control in simulated marine environment
- 2016Active and passive protection of AA2024-T3 by a hybrid inhibitor doped mesoporous sol-gel and top coating systemcitations
- 2015Active and passive corrosion protection of AA2024-T3 by an hybrid inhibitor doped mesoporous sol-gel and top coating system
- 2015Active and passive corrosion protection of AA2024-T3 by an hybrid inhibitor doped mesoporous sol-gel and top coating system
- 2015On the application of scanning microelectrochemical techniques to study the active protection offered by inhibitor loaded mesoporous sol-gel films
- 2015Active corrosion protection of AA2024-T3 by an hybrid inhibitor doped mesoporous sol-gel and top coating system
- 2011A combined mechanical, microscopic and local electrochemical evaluation of self-healing properties of shape-memory polyurethane coatings (available online)
Places of action
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article
Albumin Protein Impact on Early-Stage In Vitro Biodegradation of Magnesium Alloy (WE43)
Abstract
Mg and its alloys are promising biodegradable materials for orthopedic implants and cardiovascular stents. The first interactions of protein molecules with Mg alloy surfaces have a substantial impact on their biocompatibility and biodegradation. We investigate the early-stage electrochemical, chemical, morphological, and electrical surface potential changes of alloy WE43 in either 154 mM NaCl or Hanks’ simulated physiological solutions in the absence or presence of bovine serum albumin (BSA) protein. WE43 had the lowest electrochemical current noise (ECN) fluctuations, the highest noise resistance (Zn = 1774 Ω·cm2), and the highest total impedance (|Z| = 332 Ω·cm2) when immersed for 30 min in Hanks’ solution. The highest ECN, lowest Zn (1430 Ω·cm2), and |Z| (49 Ω·cm2) were observed in the NaCl solution. In the solutions containing BSA, a unique dual-mode biodegradation was observed. Adding BSA to a NaCl solution increased |Z| from 49 to 97 Ω·cm2 and decreased the ECN signal of the alloy, i.e., the BSA inhibited corrosion. On the other hand, the presence of BSA in Hanks’ solution increased the rate of biodegradation by decreasing both Zn and |Z| while increasing ECN. Finally, using scanning Kelvin probe force microscopy (SKPFM), we observed an adsorbed nanolayer of BSA with aggregated and fibrillar morphology only in Hanks’ solution, where the electrical surface potential was 52 mV lower than that of the Mg oxide layer.