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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Burriel, Mónica
Université Grenoble Alpes
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2024Optimizing YSZ Electrolyte Deposition via MOCVD for Enhanced Thin Film Solid Oxide Cells ; Optimisation de la déposition d'electrolyte de YSZ par MOCVD pour des cellules à oxydes solides en couche mince performantes
- 2024Tuning the synaptic properties of TiN/La2NiO4+δ/Pt memristive devices by post-deposition annealing
- 2024Impact of the La 2 NiO 4+δ Oxygen Content on the Synaptic Properties of the TiN/La 2 NiO 4+δ /Pt Memristive Devices
- 2024Impact of the La2NiO4+d oxygen content on the synaptic properties of the TiN/La2NiO4+d/Pt memristive devices
- 2024A self-assembled multiphasic thin film as an oxygen electrode for enhanced durability in reversible solid oxide cellscitations
- 2023Non-Volatile Bipolar TiN/LaMnO3/Pt Memristors with Optimized Performancecitations
- 2022A cobaltite-based thin film nanocomposite funcional layer wiht enhanced electrochemical stability for solid oxide cells
- 2022Nanostructured La 0.75 Sr 0.25 Cr 0.5 Mn 0.5 O 3 -Ce 0.8 Sm 0.2 O 2 Heterointerfaces as All-Ceramic Functional Layers for Solid Oxide Fuel Cell Applicationscitations
- 2022Tailored nano-columnar La2NiO4 cathodes for improved electrode performancecitations
- 2022Structural defects improve the memristive characteristics of epitaxial La$_{0.8}$Sr$_{0.2}$MnO$_ {3-delta}$ based devicescitations
- 2022Nanostructured La0.75Sr0.25Cr0.5Mn0.5O3–Ce0.8Sm 0.2O2 Heterointerfaces as All-Ceramic Functional Layers for Solid Oxide Fuel Cell Applicationscitations
- 2022La$_2$NiO$_{4+delta}$ ‐based memristive devices integrated on Si‐based substratescitations
- 2019Microscopic Mechanisms of Local Interfacial Resistive Switching in LaMnO 3+δcitations
- 2016Rational design of hierarchically nanostructured electrodes for solid oxide fuel cellscitations
- 2010Influence of the Microstructure on the High-Temperature Transport Properties of GdBaCo2O5.5+δ Epitaxial Filmscitations
- 2010BSCF epitaxial thin films: Electrical transport and oxygen surface exchangecitations
- 2008Electrical conductivity and oxygen exchange kinetics of La2NiO4+ thin films grown by chemical vapor depositioncitations
Places of action
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article
Nanostructured La0.75Sr0.25Cr0.5Mn0.5O3–Ce0.8Sm 0.2O2 Heterointerfaces as All-Ceramic Functional Layers for Solid Oxide Fuel Cell Applications
Abstract
The use of nanostructured interfaces and advanced functional materials opens up a new playground in the field of solid oxide fuel cells. In this work, we present two all-ceramic thin-film heterostructures based on samarium-doped ceria and lanthanum strontium chromite manganite as promising functional layers for electrode application. The films were fabricated by pulsed laser deposition as bilayers or self-assembled intermixed nanocomposites. The microstructural characterization confirmed the formation of dense, well-differentiated, phases and highlighted the presence of strong cation intermixing in the case of the nanocomposite. The electrochemical properties─solid/gas reactivity and in-plane conductivity─are strongly improved for both heterostructures with respect to the single-phase constituents under anodic conditions (up to fivefold decrease of area-specific resistance and 3 orders of magnitude increase of in-plane conductivity with respect to reference single-phase materials). A remarkable electrochemical activity was also observed for the nanocomposite under an oxidizing atmosphere, with no significant decrease in performance after 400 h of thermal aging. This work shows how the implementation of nanostructuring strategies not only can be used to tune the properties of functional films but also results in a synergistic enhancement of the electrochemical performance, surpassing the parent materials and opening the field for the fabrication of high-performance nanostructured functional layers for application in solid oxide fuel cells and symmetric systems