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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Anasori, Babak
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2024Electro‐Conductive Ti<sub>3</sub>C<sub>2</sub> MXene Multilayered Membranes: Dye Removal and Antifouling Performancecitations
- 2024Treatment of carbon electrodes with Ti3C2Tx MXene coating and thermal method for vanadium redox flow batteries : a comparative studycitations
- 2021Nacre-Mimetic, Mechanically Flexible, and Electrically Conductive Silk Fibroin-MXene Composite Foams as Piezoresistive Pressure Sensorscitations
- 2020In Situ N-Doped Graphene and Mo Nanoribbon Formation from Mo2Ti2C3 MXene Monolayers
- 2018Cold Sintered Ceramic Nanocomposites of 2D MXene and Zinc Oxidecitations
- 2018Stamping of Flexible, Coplanar Micro-Supercapacitors Using MXene Inkscitations
- 2018Layer-by-layer assembly of MXene and carbon nanotubes on electrospun polymer films for flexible energy storagecitations
- 2017Asymmetric Flexible MXene-Reduced Graphene Oxide Micro-Supercapacitorcitations
- 2017Thermoelectric Properties of Two-Dimensional Molybdenum-based MXenescitations
- 2015Experimental and theoretical characterization of ordered MAX phases Mo2TiAlC2 and Mo2Ti2AlC3citations
Places of action
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article
Nacre-Mimetic, Mechanically Flexible, and Electrically Conductive Silk Fibroin-MXene Composite Foams as Piezoresistive Pressure Sensors
Abstract
<p>The hierarchical nacre-like three-dimensional (3D) assembly of porous and lightweight materials is in high demand for applications such as sensors, flexible energy storage and harvesting devices, electromagnetic interference shielding, and biomedical applications. However, designing such a biomimetic hierarchical architecture is highly challenging due to the lack of experimental approaches to achieve the necessary control over the materials' microstructure on the multilength scale. Aerogels and foam-based materials have recently been developed as attractive candidates for pressure-sensing applications. However, despite recent progress, the bottleneck for these materials to achieve electrical conductivity combined with high mechanical flexibility and fast strain recovery remains. In this study, for the first time, inspired by the multiscale architecture of nacre, we fabricated a series of ultralightweight, flexible, electrically conductive, and relatively high-strength composite foams through hybridizing the cross-linked silk fibroin (SF) biopolymer, extracted from Bombyx mori silkworm cocoon, reinforced with two-dimensional graphene oxide (GO) and Ti3C2 MXene nanosheets. Nacre is a naturally porous material with a lightweight, mechanically robust network structure, thanks to its 3D interconnected lamella-bridge micromorphology. Inspired by this material, we assemble a cross-linked SF fibrous solution with MXene and GO nanosheets into nacre-like architecture using a bidirectional freeze-casting technique. Subsequent freeze-drying and gas-phase hydrophobization resulted in composite foams with 3D hierarchical porous architectures with a unique combination of mechanical resilience, electrical conductance, and ultra-lightness. The developed composite presented excellent performances as piezoresistive pressure-sensing devices and sorbents for oil/water separation, which indicated great potential in mechanically switchable electronics.</p>