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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lundström, Mari
Aalto University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (41/41 displayed)
- 2024Graphite recovery from waste Li-ion battery black mass for direct re-usecitations
- 2023Recent developments of electrodeposition-redox replacement in metal recovery and functional materials: A reviewcitations
- 2023Assessment of environmental sustainability of nickel required for mobility transitioncitations
- 2023Assessment of environmental sustainability of nickel required for mobility transitioncitations
- 2023Flowsheet design and environmental impacts of cobalt co-product recovery from complex Au-Co orescitations
- 2023Emeraldine Salt-Nanocarbon Composites as a Material for Copper Recovery from Industrial Wastewaters
- 2022Carbon Nanotube-Based Thermoelectric Modules Enhanced by ZnO Nanowirescitations
- 2022Electrochemical Growth of Ag/Zn Alloys from Zinc Process Solutions and Their Dealloying Behaviorcitations
- 2022A New Hydrometallurgical Process for Metal Extraction from Electric Arc Furnace Dust Using Ionic Liquidscitations
- 2022Green and Controllable Preparation of Cu/Zn Alloys Using Combined Electrodeposition and Redox Replacementcitations
- 2022Targeted surface modification of Cu/Zn/Ag coatings and Ag/Cu particles based on sacrificial element selection by electrodeposition and redox replacementcitations
- 2021Cyclic voltammetry and potentiodynamic polarization studies of chalcopyrite concentrate in glycine mediumcitations
- 2021Performance-Based Selection of the Cathode Material for the Electrodeposition-Redox Replacement Process of Gold Recovery from Chloride Solutionscitations
- 2021Copper cathode contamination by nickel in copper electrorefiningcitations
- 2021Biopolymeric Anticorrosion Coatings from Cellulose Nanofibrils and Colloidal Lignin Particlescitations
- 2021Copper recovery from industrial wastewater - Synergistic electrodeposition onto nanocarbon materialscitations
- 2020Mechanism of selective gold extraction from multi-metal chloride solutions by electrodeposition-redox replacementcitations
- 2020Mechanism of selective gold extraction from multi-metal chloride solutions by electrodeposition-redox replacementcitations
- 2020A sustainable two-layer lignin-anodized composite coating for the corrosion protection of high-strength low-alloy steelcitations
- 2020Transformation of industrial wastewater into copper–nickel nanowire composites : straightforward recycling of heavy metals to obtain products of high added valuecitations
- 2020Investigation of the anticorrosion performance of lignin coatings after crosslinking with triethyl phosphate and their adhesion to a polyurethane topcoat
- 2019Energy efficient copper electrowinning and direct deposition on carbon nanotube film from industrial wastewaterscitations
- 2019Sulfation Roasting Mechanism for Spent Lithium-Ion Battery Metal Oxides Under SO2-O2-Ar Atmospherecitations
- 2019Modelling of silver anode dissolution and the effect of gold as impurity under simulated industrial silver electrorefining conditionscitations
- 2018A Sustainable Methodology for Recycling Electric Arc Furnace Dustcitations
- 2018Structural distinction due to deposition method in ultrathin films of cellulose nanofibrescitations
- 2018From waste to valuable resource: Lignin as a sustainable anti-corrosion coatingcitations
- 2018A direct synthesis of platinum/nickel co-catalysts on titanium dioxide nanotube surface from hydrometallurgical-type process streamscitations
- 2018Corrosion behaviour of cast and deformed copper-carbon nanotube composite wires in chloride mediacitations
- 2018Selective reductive leaching of cobalt and lithium from industrially crushed waste Li-ion batteries in sulfuric acid systemcitations
- 2018Kinetic study and modelling of silver dissolution in synthetic industrial silver electrolyte as a function of electrolyte composition and temperaturecitations
- 2018Carbon Nanotube Fiber Pretreatments for Electrodeposition of Coppercitations
- 2018Jarogain Process:A Hydrometallurgical Option to Recover Metal Values from RLE Zinc Residue and Steel Dust
- 2018Hydrometallurgical approach for leaching of metals from copper rich side stream originating from base metal productioncitations
- 2018Platinum recovery from Industrial Process Solutions by Electrodepo-sition-Redox Replacement
- 2017Designing gold extraction processes:Performance study of a case-based reasoning systemcitations
- 2017Designing gold extraction processes: performance study of a case-based reasoning systemcitations
- 2017Leaching of Sb from TROF furnace Doré slagcitations
- 2017Simulation of electrochemical processes during oxygen evolution on Pb-MnO2 composite electrodescitations
- 2017Primary Copper Smelter and Refinery as a Recycling Plant—A System Integrated Approach to Estimate Secondary Raw Material Tolerancecitations
- 2016Carbon nanotube-copper composites by electrodeposition on carbon nanotube fiberscitations
Places of action
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article
Biopolymeric Anticorrosion Coatings from Cellulose Nanofibrils and Colloidal Lignin Particles
Abstract
<p>This study presents a process for preparation of cellulose-lignin barrier coatings for hot-dip galvanized (HDG) steel by aqueous electrophoretic deposition. Initially, a solution of softwood kraft lignin and diethylene glycol monobutyl ether was used to prepare an aqueous dispersion of colloidal lignin particles (CLPs) via solvent exchange. Analysis of the dispersion showed that it comprised submicron particles (D = 146 nm) with spherical morphologies and colloidal stability (ζ-potential = -40 mV). Following successful formation, the CLP dispersion was mixed with a suspension of TEMPO-oxidized cellulose nanofibers (TOCN, 1 and 2 g·L<sup>-1</sup>) at a fixed volumetric ratio (1:1, TOCN-CLPs), and biopolymers were deposited onto HDG steel surfaces at different potentials (0.5 and 3 V). The effects of these variables on coating formation, dry adhesion, and electrochemical properties (3.5% NaCl) were investigated. The scanning electron microscopy results showed that coalescence of CLPs occurs during the drying of composite coatings, resulting in formation of a barrier layer on HDG steel. The scanning vibrating electrode technique results demonstrated that the TOCN-CLP layers reduced the penetration of the electrolyte (3.5% NaCl) to the metal-coating interface for at least 48 h of immersion, with a more prolonged barrier performance for 3 V-deposited coatings. Additional electrochemical impedance spectroscopy studies showed that all four coatings provided increased levels of charge transfer resistance (R<sub>ct</sub>) - compared to bare HDG steel - although coatings deposited at a higher potential (3 V) and a higher TOCN concentration provided the maximum charge transfer resistance after 15 days of immersion (13.7 cf. 0.2 kΩ·cm<sup>2</sup> for HDG steel). Overall, these results highlight the potential of TOCN-CLP biopolymeric composites as a basis for sustainable corrosion protection coatings. </p>