| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Fichtner, Maximilian
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (26/26 displayed)
- 2024Synthesis, Structural Analysis, and Degradation Behavior of Potassium Tin Chloride as Chloride‐Ion Batteries Conversion Electrode Material
- 2023High Active Material Loading in Organic Electrodes Enabled by an in‐situ Electropolymerized π‐Conjugated Tetrakis (4‐Aminophenyl) Porphyrincitations
- 2023Synthesis and Structure Stabilization of Disordered Rock Salt Mn/V-Based Oxyfluorides as Cathode Materials for Li-Ion Batteries
- 2023Synthesis of perovskite-type high-entropy oxides as potential candidates for oxygen evolution
- 2023Addressing the Sluggish Kinetics of Sulfur Redox for High‐Energy Mg–S Batteriescitations
- 2023Addressing the Sluggish Kinetics of Sulfur Redox for High‐Energy Mg–S Batteriescitations
- 2023A π‐Conjugated Porphyrin Complex as Cathode Material Allows Fast and Stable Energy Storage in Calcium Batteriescitations
- 2023A π‐Conjugated Porphyrin Complex as Cathode Material Allows Fast and Stable Energy Storage in Calcium Batteries
- 2023Molecular Engineering of Metalloporphyrins for High‐Performance Energy Storage: Central Metal Matterscitations
- 2023Multi‐component PtFeCoNi core‐shell nanoparticles on MWCNTs as promising bifunctional catalyst for oxygen reduction and oxygen evolution reactionscitations
- 2022Dual Role of Mo 6 S 8 in Polysulfide Conversion and Shuttle for Mg–S Batteriescitations
- 2022Synthesis of perovskite-type high-entropy oxides as potential candidates for oxygen evolutioncitations
- 2022Dual Role of Mo<sub>6</sub>S<sub>8</sub> in Polysulfide Conversion and Shuttle for Mg–S Batteriescitations
- 2021Polyoxometalate Modified Separator for Performance Enhancement of Magnesium–Sulfur Batteriescitations
- 2021A self‐conditioned metalloporphyrin as a highly stable cathode for fast rechargeable magnesium batteries
- 2021A Self‐Conditioned Metalloporphyrin as a Highly Stable Cathode for Fast Rechargeable Magnesium Batteriescitations
- 2021Surface Engineering of a Mg Electrode via a New Additive to Reduce Overpotentialcitations
- 2020Multi‐Electron Reactions Enabled by Anion‐Based Redox Chemistry for High‐Energy Multivalent Rechargeable Batteriescitations
- 2020Pseudo-ternary LiBH4-LiCl-P2S5 system as structurally disordered bulk electrolyte for all-solid-state lithium batteriescitations
- 2020Multi-electron reactions enabled by anion-participated redox chemistry for high-energy multivalent rechargeable batteriescitations
- 2020Pseudo-ternary LiBH 4 ·LiCl·P 2 S 5 system as structurally disordered bulk electrolyte for all-solid-state lithium batteriescitations
- 2020Multi‐electron reactions enabled by anion‐based redox chemistry for high‐energy multivalent rechargeable batteries
- 2019Oxygen Activity in Li-Rich Disordered Rock-Salt Oxide and the Influence of $LiNbO_{3}$ Surface Modification on the Electrochemical Performancecitations
- 2019Degradation Mechanisms in Li2VO2F Li-Rich Disordered Rock-Salt Cathodescitations
- 2019Improved cycling stability in high-capacity Li-rich vanadium containing disordered rock salt oxyfluoride cathodescitations
- 2011Structure and thermodynamic properties of the NaMgH3 perovskitecitations
Places of action
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article
Surface Engineering of a Mg Electrode via a New Additive to Reduce Overpotential
Abstract
In nonaqueous Mg batteries, inactive adsorbed species and the passivation layer formed from the reactive Mg with impurities in the electrolyte seriously affect the Mg metal/electrolyte interface. These adlayers can impede the passage of Mg$^{2+}$ ions, leading to a high Mg plating/stripping overpotential. Herein, we report the properties of a new additive, bismuth triflate (Bi(OTf)$_{3}$), for synthesizing a chlorine-free Mg electrolyte to enhance Mg plating/stripping from initial cycles. The beneficial effect of Bi(OTf)$_{3}$ can be ascribed to Bi/Mg$_{3}$Bi$_{2}$ formed in situ on the Mg metal surface, which increases the charge transfer during the on–off transition by reducing the adsorption of inactive species on the Mg surface and enhancing the resistance of the reactive surface to passivation. This simple method provides a new avenue to improve the compatibility between the Cl-free Mg electrolyte and the Mg metal anode.