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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Losic, Dusan
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2023Process intensification for gram-scale synthesis of N-doped carbon quantum dots immersing a microplasma jet in a gas-liquid reactorcitations
- 2023Sensor to Electronics Applications of Graphene Oxide through AZO Graftingcitations
- 2022Coupling graphene microribbons with carbon nanofiberscitations
- 2021Converging 2D Nanomaterials and 3D Bioprinting Technology: State‐of‐the‐Art, Challenges, and Potential Outlook in Biomedical Applicationscitations
- 2021N-doped reduced graphene oxide-PEDOT nanocomposites for implementation of a flexible wideband antenna for wearable wireless communication applicationscitations
- 2020Self-assembly and cross-linking of conducting polymers into 3D hydrogel electrodes for supercapacitor applicationscitations
- 2017From Graphene Oxide to Reduced Graphene Oxidecitations
- 2015Localized drug delivery of selenium (Se) using nanoporous anodic aluminium oxide for bone implants. citations
- 2010Platforms for controlled release of antibacterial agents facilitated by plasma polymerizationcitations
- 2010Tailoring the surface functionalities of titania nanotube arrayscitations
Places of action
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article
Self-assembly and cross-linking of conducting polymers into 3D hydrogel electrodes for supercapacitor applications
Abstract
<p>Conducting polymer hydrogels (CPH) have attracted interest for use in electronics, biomedical devices, tissue engineering, drug delivery, and energy storage thanks to their electroactivity along with an outstanding capacity to absorb large amounts of water. They are often made by polymerizing a conducting monomer in the presence of a nonconducting polymer scaffold, which can be detrimental to the electrical conductivity of the resulting polymer hydrogel. In this study, we demonstrate an innovative approach for the synthesis of conducting polymer hydrogels (CPH) without using either additives or cross-linkers, leading to conjugated polymers with enhanced electronic conductivity and large surface areas. The feasibility and versatility of our approach are demonstrated by producing a wide range of CPHs including polyaniline, polypyrrole, and poly(3,4-ethylenedioxythiophene), whose biocompatibility and electronic conductivity offer great potential for use as bioactive scaffolds for tissue regeneration and stimulation. The excellent mechanical properties of CPHs can be attributed to the intermolecular forces generated between conducting polymer chains and/or their environment that maintain the hydrogel structure, acting as self-cross-linkers. Given the outstanding charge storage properties, polyaniline hydrogel was utilized as an active material in redox supercapacitors, which delivered a high gravimetric capacitance of 492 F g<sup>-1</sup> at a current density of 1 A g<sup>-1</sup>. We have also demonstrated that polyaniline (PANi) can be used as a cross-linking agent for the preparation of a 3D graphene hydrogel with high volumetric and areal capacitances, enabling supercapacitors with excellent electrochemical performance and long-term cycling stability.</p>