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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Burn, Paul
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Publications (4/4 displayed)
- 2020Precursor route poly(1,4-phenylenevinylene)-based dopant-free interlayers for perovskite solar cellscitations
- 2018An external quantum efficiency of >20% from solution-processed poly(dendrimer) organic light-emitting diodescitations
- 2015Planar silver nanowire, carbon nanotube and PEDOT:PSS nanocomposite transparent electrodescitations
- 2015Pathway to high throughput, low cost indium-free transparent electrodescitations
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article
Precursor route poly(1,4-phenylenevinylene)-based dopant-free interlayers for perovskite solar cells
Abstract
Insoluble glycol- derivatised poly(1,4-phenylenevinylene)s (PPVs) have been prepared by in-situ thermal conversion of solution-processable xanthate precursor polymers and used as interlayers in inverted perovskite solar cells. The insolubility of the PPVs enabled the perovskite active layer to be deposited on top without dissolution and the glycol chains provided a suitable surface energy for the formation of the perovskite films. It was found that the surface of the films became more hydrophilic with increasing glycol side-chain length. The energy levels of the PPVs were consistent with their ability for hole transport and electron blocking with respect to the perovskite layer. The performance of the perovskite cells was found to be dependent on the length of PPV glycol side-chain with the optimized planar p-i-n perovskite devices incorporating the MeO-PPV interlayer exhibiting a power conversion efficiency of 12.1%.