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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Morrison, Finlay D.
University of St Andrews
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (39/39 displayed)
- 2022Structural, magnetic, and electrical properties of Bi1-xLaxMnO3 (x=0.0, 0.1, and 0.2) solid solutionscitations
- 2022Magnetically driven dielectric and structural behavior in Bi0.5La0.5FeO3citations
- 2020Stable 6H organic-inorganic hybrid lead perovskite and competitive formation of 6H and 3C perovskite structure with mixed A cationscitations
- 2019Stable 6H organic-inorganic hybrid lead perovskite and competitive formation of 6H and 3C perovskite structure with mixed A cationscitations
- 2018Quantum critical points in ferroelectric relaxors : stuffed tungsten bronze K3Li2Ta5O15 and lead pyrochlore (Pb2Nb2O7)citations
- 2018Quantum critical points in ferroelectric relaxors: Stuffed tungsten bronze K3Li2Ta5O15 and lead pyrochlore ( Pb2Nb2O7 )citations
- 2018Quantum critical points in ferroelectric relaxors:stuffed tungsten bronze K 3 Li 2 Ta 5 O 15 and lead pyrochlore (Pb 2 Nb 2 O 7 )citations
- 2017Microstructural and high-temperature impedance spectroscopy study of Ba6MNb9O30 (M=Ga, Sc, In) relaxor dielectric ceramics with tetragonal tungsten bronze structurecitations
- 2016Microstructural and high-temperature impedance spectroscopy study of Ba 6 MNb 9 O 30 (M=Ga, Sc, In) relaxor dielectric ceramics with tetragonal tungsten bronze structurecitations
- 2016Microstructural and high-temperature impedance spectroscopy study of Ba6MNb9O30 (M=Ga, Sc, In) relaxor dielectric ceramics with tetragonal tungsten bronze structurecitations
- 2016Manipulation of polar order in the “empty” tetragonal tungsten bronzes: Ba4-xSrxDy0.671.33Nb10O30, x = 0, 0.25, 0.5, 1, 2, 3citations
- 2016Manipulation of polar order in the “empty” tetragonal tungsten bronzes: Ba 4-x Sr x Dy 0.67 1.33 Nb 10 O 30 , x = 0, 0.25, 0.5, 1, 2, 3citations
- 2016Vogel-Fulcher analysis of relaxor dielectrics with the tetragonal tungsten bronze structure : Ba6MNb9O30 (M = Ga, Sc, In)citations
- 2015Effect of local A-site strain on dipole stability in A 6 GaNb 9 O 30 (A = Ba, Sr, Ca) tetragonal tungsten bronze relaxor dielectricscitations
- 2015Vogel-Fulcher analysis of relaxor dielectrics with the tetragonal tungsten bronze structure:Ba 6 MNb 9 O 30 (M = Ga, Sc, In)citations
- 2015Effect of local A-site strain on dipole stability in A6GaNb9O30 (A = Ba, Sr, Ca) tetragonal tungsten bronze relaxor dielectricscitations
- 2015Vogel-Fulcher analysis of relaxor dielectrics with the tetragonal tungsten bronze structurecitations
- 2012Structural, magnetic, and electrical properties of Bi 1-x La x MnO 3 (x=0.0, 0.1, and 0.2) solid solutionscitations
- 2012Magnetically driven dielectric and structural behavior in Bi 0.5 La 0.5 FeO 3citations
- 2012Structural, magnetic, and electrical properties of Bi1-xLaxMnO3 (x=0.0, 0.1, and 0.2) solid solutionscitations
- 2012Structural, magnetic and electrical properties of the hexagonal ferrites MFeO3 (M=Y, Yb, In)citations
- 2012Magnetically driven dielectric and structural behavior in Bi0.5La0.5FeO3citations
- 2009Leakage and Proton Conductivity in the Predicted Ferroelectric CsBiNb 2 O 7citations
- 2009Leakage and Proton Conductivity in the Predicted Ferroelectric CsBiNb2O7citations
- 2009Impedance spectroscopy studies on polycrystalline BiFeO3 thin films on Pt/Si substratescitations
- 2008Size effects on thin film ferroelectrics: Experiments on isolated single crystal sheetscitations
- 2008Submicron three-dimensional trenched electrodes and capacitors for DRAMs and FRAMscitations
- 2007Toward Self-Assembled Ferroelectric Random Access Memories:Hard-Wired Switching Capacitor Arrays with Almost Tb/in.2 Densitiescitations
- 2007Nanoscale ferroelectrics machined from single crystalscitations
- 2006Investigating the effects of reduced size on the properties of ferroelectricscitations
- 2005Exploring the fundamental effects of miniaturisation on ferroelectrics by focused ion beam processing of single crystal materialcitations
- 2005High-field conduction in barium titanatecitations
- 2005Recent materials characterizations of [2D] and [3D] thin film ferroelectric structurescitations
- 2004Intrinsic dielectric response in ferroelectric nano-capacitorscitations
- 2004Novel high capacitance materials: BaTiO3 : La and CaCu3Ti4O12citations
- 2003Ferroelectric nanotubes
- 2003New developments in ferroelectric thin filmscitations
- 2002CaCu3Ti4O12: One-step internal barrier layer capacitorcitations
- 2001Characterization of lanthanum-doped barium titanate ceramics using impedance spectroscopy
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article
Stable 6H organic-inorganic hybrid lead perovskite and competitive formation of 6H and 3C perovskite structure with mixed A cations
Abstract
We report the synthesis and properties of a new organic–inorganic hybrid lead perovskite (OIHP), azetidinium lead bromide (AzPbBr<sub>3</sub>), possessing the 6H perovskite structure (space group <i>P</i>6<sub>3</sub>/<i>mmc</i> with <i>a</i> = 8.745 Å and <i>c</i> = 21.329 Å). This compound has a band gap of 2.81 eV and remains stable for >6 months in the ambient environment. DFT simulations are in fairly good agreement with experiments and indicate that AzPbBr<sub>3</sub> is a direct band gap semiconductor. A partial solid solution with the cubic (3C) perovskite methylammonium lead bromide (Az<sub>1–<i>x</i></sub>MA<sub><i>x</i></sub>PbBr<sub>3</sub>) is possible. In Az-rich 6H compositions the lattice volume and band gap are invariant with <i>x</i> (≤0.3), whereas in the MA-rich 3C phase (0.8 ≤ <i>x</i> ≤ 1.0) the lattice parameters and band gap increase with increasing Az content. Although the relatively large band gap of AzPbBr<sub>3</sub> makes it unsuitable for photovoltaic applications, the results indicate Az<sup>+</sup> is a suitable alternative organic A cation for band gap tuning of OHIPs.