| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Verbeeck, Jo
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (22/22 displayed)
- 2024Phase coexistence induced surface roughness in V<sub>2</sub>O<sub>3</sub>/Ni magnetic heterostructurescitations
- 2024Stabilizing Perovskite Pb(Mg<sub>0.33</sub>Nb<sub>0.67</sub>)O<sub>3</sub>-PbTiO<sub>3</sub> Thin Films by Fast Deposition and Tensile Mismatched Growth Templatecitations
- 2023Low-Dose 4D-STEM Tomography for Beam-Sensitive Nanocompositescitations
- 2022On the formation mechanisms of intragranular shear bands in olivine by stress-induced amorphizationcitations
- 2021Optical versus electron diffraction imaging of Twist-angle in 2D transition metal dichalcogenide bilayerscitations
- 2021Increased performance improvement of lithium-ion batteries by dry powder coating of high-nickel NMC with nanostructured fumed ternary lithium metal oxidescitations
- 2020Single femtosecond laser pulse excitation of individual cobalt nanoparticlescitations
- 2020Reliable Characterization of Organic and Pharmaceutical Compounds with High Resolution Monochromated EEL Spectroscopycitations
- 2020Unravelling stacking order in epitaxial bilayer MX₂ using 4D-STEM with unsupervised learningcitations
- 2019Controlling the interfacial conductance in <tex>$LaAlO_{3}/SrTiO_{3}$</tex> in 90 degrees off-axis sputter depositioncitations
- 2018Getting rid of anti-solvents: gas quenching for high performance perovskite solar cellscitations
- 2017Energy level alignment and cation charge states at the <tex>$LaFeO_{3}/LaMnO_{3}$</tex> (001) heterointerfacecitations
- 2017One step toward a new generation of C-MOS compatible oxide PN junctionscitations
- 2017Direct observation of enhanced magnetism in individual size- and shape-selected 3d transition metal nanoparticlescitations
- 2016A universal deposition protocol for planar heterojunction solar cells with high efficiency based on hybrid lead halide perovskite familiescitations
- 2016Long-range domain structure and symmetry engineering by interfacial oxygen octahedral coupling at heterostructure interfacecitations
- 2016Engineering properties by long range symmetry propagation initiated at perovskite heterostructure interface
- 2015Co-rich ZnCoO nanoparticles embedded in wurtzite <tex>$Zn_{1-x}Co_{x}O$</tex> thin filmscitations
- 2014Crystal Structure and Luminescent Properties of R2-xEux(MoO4)(3) (R = Gd, Sm) Red Phosphorscitations
- 2014Influence of the structure on the properties of <tex>$Na_{x}Eu_{y}(MoO_{4})_{z}$</tex> red phosphorscitations
- 2012Artificial construction of the layered Ruddlesden–Popper Manganite La2Sr2Mn3O10by reflection high energy electron diffraction monitored pulsed laser deposition
- 2012Grain size tuning of nanocrystalline chemical vapor deposited diamond by continuous electrical bias growth: Experimental and theoretical studycitations
Places of action
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article
Increased performance improvement of lithium-ion batteries by dry powder coating of high-nickel NMC with nanostructured fumed ternary lithium metal oxides
Abstract
Dry powder coating is an effective approach to protect the surfaces of layered cathode active materials (CAMs) in lithium-ion batteries. Previous investigations indicate an incorporation of lithium ions in fumed Al2O3, ZrO2, and TiO2 coatings on LiNi0.7Mn0.15Co0.15O2 during cycling, improving the cycling performance. Here, this coating approach is transferred for the first time to fumed ternary LiAlO2, Li4Zr3O8, and Li4Ti5O12 and directly compared with their lithium-free equivalents. All materials could be processed equally and their nanostructured small aggregates accumulate on the CAM surfaces to quite homogeneous coating layers with a certain porosity. The LiNixMnyCozO2 (NMC) coated with lithium-containing materials shows an enhanced improvement in overall capacity, capacity retention, rate performance, and polarization behavior during cycling, compared to their lithium-free analogues. The highest rate performance was achieved with the fumed ZrO2 coating, while the best long-term cycling stability with the highest absolute capacity was obtained for the fumed LiAlO2-coated NMC. The optimal coating agent for NMC to achieve a balanced system is fumed Li4Ti5O12, providing a good compromise between high rate capability and good capacity retention. The coating agents prevent CAM particle cracking and degradation in the order LiAlO2 ≈ Al2O3 > Li4Ti5O12 > Li4Zr3O8 > ZrO2 > TiO2. A schematic model for the protection and electrochemical performance enhancement of high-nickel NMC with fumed metal oxide coatings is sketched. It becomes apparent that physical and chemical characteristics of the coating significantly influence the performance of NMC. A high degree of coating-layer porosity is favorable for the rate capability, while a high coverage of the surface, especially in vulnerable grain boundaries, enhances the long-term cycling stability and improves the cracking behavior of NMCs. While zirconium-containing coatings possess the best chemical properties for high rate performances, aluminum-containing coatings feature a superior chemical nature to protect high-nickel NMCs.